|Publication number||US5958098 A|
|Application number||US 08/946,506|
|Publication date||Sep 28, 1999|
|Filing date||Oct 7, 1997|
|Priority date||Oct 7, 1997|
|Publication number||08946506, 946506, US 5958098 A, US 5958098A, US-A-5958098, US5958098 A, US5958098A|
|Inventors||Leung K. Heung|
|Original Assignee||Westinghouse Savannah River Company|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (17), Referenced by (43), Classifications (11), Legal Events (10)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the United States Department of Energy and Westinghouse Savannah River Company.
1. Field of the Invention
The invention relates generally to the field of metals and metal alloys that can react with hydrogen to form metal hydrides.
2. Description of Related Art
Metals and metal alloys that are capable of reacting with hydrogen to form a hydride are known as hydride formers or simply metal hydrides. Examples of hydride formers include most elemental metals and their associated alloys. Many of these materials have found applications in hydrogen storage, hydrogen recovery from gas mixtures and energy conversion systems. Unfortunately, these materials suffer from two significant disadvantages:
First, when these metals and alloys react with hydrogen repeatedly, they crack into pieces or break into particles as small as fractions of a micron known as "fines." If they are used as membranes or filters separating hydrogen from other gases, such breaking will cause the filter to fail. If they are used in packed columns or beds for hydrogen storage or absorption, such breaking can cause excessive resistance to gas flow or even a blockage.
A second disadvantage to hydride formers is that they are often sensitive to poisons like carbon monoxide and sulfur compounds and to reactive gases like oxygen. Commercial hydrogen streams contain small amounts of these impurities that prevent the application of metal hydrides in those areas.
The prior art is replete with inventions using metal hydrides to filter hydrogen from a diverse gaseous stream. For example, U.S. Pat. No. 3,793,435 to Reilly et al. teaches the use of lanthanum alloy hydrides for separation of hydrogen from other gases. U.S. Pat. No. 4,108,605 teaches the use of metal hydrides to adsorb hydrogen and impurities from a gaseous stream and then through temperature manipulation to release the hydrogen while retaining the impurities.
While these inventions are useful in purifying hydrogen streams, they still suffer from the physical integrity and impurity sensitivity drawbacks discussed above. Thus, there is room in the art for improvements directed towards improving the dimensional stability and resistance to impurities of metal hydrides.
One object of the present invention is to provide a method for embedding metal hydride particles in a network of silica particles.
Another object is that the method produce a silica embedded metal hydride that is dimensionally stable.
A further object is that the method produce a silica embedded metal hydride that is resistant to poisons and impurities.
Yet another object is to provide a composition for separating hydrogen from a diverse stream of gases such as H2, N2, Methane, Ethane, CO2, CO and H2 S.
Still another object is that the composition resist breaking into fines and that any fines that are produced be held in the silica network.
According to the present invention, the foregoing and other objects and advantages are attained by a silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid.
In accordance with one aspect of the invention, the solid is ground into granules for use of the product in hydrogen storage and separation.
In accordance with another aspect of the invention, the paste is molded into plates or cylinders and then dried for use of the product as a hydrogen filter.
In accordance with yet another aspect of the invention, the paste is impregnated in a porous substrate or wire network for applications where mechanical strength is required.
In accordance with a further aspect of the invention, a liquid that is non-soluble in water is added to the paste to enhance the processing of the composition.
In accordance with a still further aspect of the invention, the composition is heat treated to adjust its porosity and mechanical strength.
Additional objects and advantages will become apparent from a consideration of the following description.
According to a preferred embodiment of the present invention, a silica embedded metal hydride composition comprises a porous network of small, amorphous fumed silica particles into which metal hydride particles are embedded. The composition is dimensionally stable and is resistant to oxygen, poisons and reactive impurities. A method for making the composition that achieves all the various objects of the present invention will now be described.
The process begins by providing a pre-determined amount of amorphous fumed silica. This substance is high purity silicon oxide (SiO2) and is commercially available, such as CAB-O-SilŪ grade EH-5 from CABOT Corporation. Fumed silica is formed by burning silicon tetrachloride vapor in a flame of hydrogen and oxygen.
The fumed silica is then blended into water to form a paste via a polymerization process. The weight ratio of water to fumed silica can range from 3:1 to 9:1. Metal hydride particles are added to the paste to be embedded into the silica network. The weight ratio of the metal hydride particles to the fumed silica in the paste ranges from 0.18:1 to 2.3:1. In practice, the metal hydride typically comprises 15% to 70% of the finished product by weight. Preferably, the metal hydride particles have sizes ranging from 0.5 μm to 100 μm, and most preferably, the particles are smaller than 50 μm. Examples of hydrides that can be used in the composition include pure hydrides such as Pd and more complex alloys of Pd, Ti, La, Ni, Zr, Co and Al. U.S. Pat. No. 5,443,616 to Congdon describes a method for producing metal hydrides in the form of fine particles suitable for use in the instant invention and is incorporated herein by reference.
According to one embodiment of the invention, the paste is then allowed to dry to form a solid. The simplest method for drying the paste is to allow it to air dry. However, using heat and/or vacuum drying techniques may provide additional beneficial properties. Next, the solid composition is ground up using a commercial grinder, grain mill or simply a mortar and pestle. Typically the ground up solid is filtered through a sieve to collect granules of a desired size for packing into columns or beds commonly used in hydrogen storage or separations systems.
If desired, the ground up solid can be added back into a new paste of fumed silica and then dried and ground up to form a composition having a double layer of silica with metal hydride particles embedded in the layers. It should be obvious to one skilled in the art that this process can be repeated to generate a composition having multiple silica layers.
Alternatively, the paste can be poured into a mold and then dried using the techniques discussed above to form plates, cylinders, or other desired forms for use in filtering hydrogen from other gases.
For applications where mechanical strength is critical, the paste can be impregnated in a porous substrate or wire network and once again dried using the techniques discussed above. Advantageously, the paste is quite versatile and is readily adaptable for use in a variety of applications.
According to another embodiment of the invention, greater resistance to oxygen and other impurities, a liquid that is non-soluble in water can be added to the paste. Examples of such liquids include common paint thinner and mineral oil spirit type 11, grade A. The non-soluble liquid has the effect of breaking down the paste into particulates that can then be dried using the techniques discussed above. The following steps describe one specific embodiment of the invention incorporating the non-soluble liquid:
First, acquire 85 grams of fumed silica, 33 grams of LaNi4.25 Al0.75 powder (metal hydride) having a particle size ≦45 μm and 351 grams of deionized water. The water is then placed in a blender at median speed. Add the fumed silica and the metal hydride to the water gradually until the entire amount is added and a uniform paste is formed. Switch the blender to low speed and pour into the paste 170 cc of paint thinner (non-soluble liquid). Continue blending until the paste is broken into particulates. The particulates can then be removed from the blender and dried using the techniques discussed above. In addition, the particulates can be ground up and run through a sieve to collect a preferred granule size for the final product.
If desired, the final product based on the embodiments discussed above can be heat treated in the presence of an inert noble gas such as He or Ar to adjust the porosity or mechanical strength of the composition. This heat treating process is known as sintering.
In the final product, the silica particles form a porous network via polymerization of the silica molecules at contacting points. The size of the pores in the network is typically between 1 and 100 nanometers. In contrast, the metal hydride particles are only 0.5 μm (fines) to 100 μm large. Since the metal hydride particles are 5 to 1000 times larger than the silica pores, the metal hydride particles are easily retained in the network. When the product is exposed to a gas mixture containing hydrogen and other gases or undesirable impurities, the hydrogen is able to pass freely through the pores of the network because of its small molecular size. Conversely, the larger molecules of the other gases or impurities are filtered by the silica network from reaching the metal hydride particles held therein. Thus, the product can be freely exposed to the atmosphere without fear of oxidizing the embedded metal hydride. Experiments have revealed that the product can even filter CO molecules with some degree of success. In addition to acting as a filter, the silica network also provides dimensional stability to the metal hydrides to curb their tendency to break into fines after repeated exposure to hydrogen. Although the silica network cannot prevent the formation of fines entirely, any fines that are produced are held within the network and prevented from finding their way into the hydrogen storage equipment causing resistance to gas flow or even plugging up the system. Additional details and comparisons are set forth in Table 1.
TABLE 1______________________________________ Particle Size In the change after Hydrogen presence repeated hydro- absorption after of 10% CO gen absorption exposure to air in hydrogen______________________________________Pure metal Ranges from Does not absorb Does nothydride original size hydrogen for 20 absorb(LaNi4.25 Al0.75) down to micron minutes, then only hydrogen range slowly after 20 minutesComposition of No change in size Absorbs hydrogen Absorbsthe invention immediately hydrogen(metal hydride to 70% ofembedded in originalfumed silica) capacity______________________________________
The above description is given in reference to a silica embedded metal hydride composition and method for making same. However, it is understood that many variations are apparent to one of ordinary skill in the art from a reading of the above specification and such variations are within the spirit and scope of the invention as defined by the following appended claims:
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|U.S. Classification||55/523, 95/127, 55/DIG.5, 95/56, 55/524|
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