Nanda, KK (2006) A simple classical approach for the melting temperature of inert-gas nanoparticles. In: Chemical Physics Letters, 419 (1-3). pp. 195-200.
5626.pdf - Published Version
Restricted to Registered users only
Download (140Kb) | Request a copy
Like the metal and semiconductor nanoparticles, the melting temperature of free inert-gas nanoparticles decreases with decreasing size. The variation is linear with the inverse of the particle size for large nanoparticles and deviates from the linearity for small nanoparticles. The decrease in the melting temperature is slower for free nanoparticles with non-wetting surfaces, while the decrease is faster for nanoparticles with wetting surfaces. Though the depression of the melting temperature has been reported for inert-gas nanoparticles in porous glasses, superheating has also been observed when the nanoparticles are embedded in some matrices. By using a simple classical approach, the influence of size, geometry and the matrix on the melting temperature of nanoparticles is understood quantitatively and shown to be applicable for other materials. It is also shown that the classical approach can be applied to understand the size-dependent freezing temperature of nanoparticles.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Elsevier Science.|
|Department/Centre:||Division of Chemical Sciences > Materials Research Centre|
|Date Deposited:||16 Sep 2010 09:54|
|Last Modified:||19 Sep 2010 06:15|
Actions (login required)