by Staff Writers
Upton NY (SPX) Aug 06, 2014
Using a new method to track the electrochemical reactions in a common electric vehicle battery material under operating conditions, scientists at the U.S. Department of Energy's Brookhaven National Laboratory have revealed new insight into why fast charging inhibits this material's performance.
The study also provides the first direct experimental evidence to support a particular model of the electrochemical reaction. The results, published in Nature Communications, could provide guidance to inform battery makers' efforts to optimize materials for faster-charging batteries with higher capacity.
"Our work was focused on developing a method to track structural and electrochemical changes at the nanoscale as the battery material was charging," said Brookhaven physicist Jun Wang, who led the research. Her group was particularly interested in chemically mapping what happens in lithium iron phosphate- a material commonly used in the cathode, or positive electrode, of electrical vehicle batteries-as the battery charged.
"We wanted to catch and monitor the phase transformation that takes place in the cathode as lithium ions move from the cathode to the anode," she said.
Getting as many lithium ions as possible to move from cathode to anode through this process, known as delithiation, is the key to recharging the battery to its fullest capacity so it will be able to provide power for the longest possible period of time. Understanding the subtle details of why that doesn't always happen could ultimately lead to ways to improve battery performance, enabling electric vehicles to travel farther before needing to be recharged.
X-ray imaging and chemical fingerprinting
To improve upon those methods, the Brookhaven team used a combination of full- field, nanoscale-resolution transmission x-ray microscopy (TXM) and x-ray absorption near-edge spectroscopy (XANES) at the National Synchrotron Light Source (NSLS), a DOE Office of Science User Facility that provides beams of high-intensity x-rays for studies in many areas of science.
These x-rays can penetrate the material to produce both high-resolution images and spectroscopic data-a sort of electrochemical "fingerprint" that reveals, pixel by pixel, where lithium ions remain in the material, where they've been removed leaving only iron phosphate, and other potentially interesting electrochemical details.
The scientists used these methods to analyze samples made up of multiple nanoscale particles in a real battery electrode under operating conditions (in operando). But because there can be a lot of overlap of particles in these samples, they also conducted the same in operando study using smaller amounts of electrode material than would be found in a typical battery.
This allowed them to gain further insight into how the delithiation reaction proceeds within individual particles without overlap. They studied each system (multi-particle and individual particles) under two different charging scenarios-rapid (like you'd get at an electric vehicle recharging station), and slow (used when plugging in your vehicle at home overnight).
Insight into why charging rate matters
That is, in some regions of the electrode, all the lithium ions are removed leaving only iron phosphate behind, while particles in other areas show no change at all, retaining their lithium ions. Even in the "fully charged" state, some particles retain lithium and the electrode's capacity is well below the maximum level.
"This is the first time anyone has been able to see that delithiation was happening differently at different spatial locations on an electrode under rapid charging conditions," Jun Wang said.
Slower charging, in contrast, results in homogeneous delithiation, where lithium iron phosphate particles throughout the electrode gradually change over to pure iron phosphate-and the electrode has a higher capacity.
Implications for better battery design
For example, the phase transformation may happen more efficiently in some parts of the electrode than others due to inconsistencies in the physical structure or composition of the electrode-for example, its thickness or how porous it is.
"So rather than focusing only on the battery materials' individual features, manufacturers might want to look at ways to prepare the electrode so that all parts of it are the same, so all particles can be involved in the reaction instead of just some," he said.
The individual-particle study also detected, for the first time, the coexistence of two distinct phases-lithiated iron phosphate and delithiated, or pure, iron phosphate-within single particles. This finding confirms one model of the delithiation phase transformation-namely that it proceeds from one phase to the other without the existence of an intermediate phase.
"These discoveries provide the fundamental basis for the development of improved battery materials," said Jun Wang. "In addition, this work demonstrates the unique capability of applying nanoscale imaging and spectroscopic techniques in understanding battery materials with a complex mechanism in real battery operational conditions."
The paper notes that this in operando approach could be applied in other fields, such as studies of fuel cells and catalysts, and in environmental and biological sciences.
Future studies using these techniques at NSLS-II-which will produce x-rays 10,000 times brighter than those at NSLS-will have even greater resolution and provide deeper insight into the physical and electrochemical characteristics of these materials, thus making it possible for scientists to further elucidate how those properties affect performance.
Yu-chen Karen Chen-Wiegart also contributed to this research. This work was supported by a Laboratory Directed Research and Development (LDRD) project at Brookhaven National Laboratory. The use of the NSLS was supported by the U.S. Department of Energy's Office of Science.
Brookhaven National Laboratory
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