|Número de publicación||US3940529 A|
|Tipo de publicación||Concesión|
|Número de solicitud||US 05/376,383|
|Fecha de publicación||24 Feb 1976|
|Fecha de presentación||5 Jul 1973|
|Fecha de prioridad||5 Jul 1973|
|Número de publicación||05376383, 376383, US 3940529 A, US 3940529A, US-A-3940529, US3940529 A, US3940529A|
|Inventores||Richard R. Hepford, Clifford J. Roberts, Jr.|
|Cesionario original||Scott Paper Company|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (4), Citada por (88), Clasificaciones (30)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
1. Field of the Invention
The invention relates to an absorbent fibrous sheet material made from two or more webs plied together and to a method and apparatus for forming it. Such webs are preferably made from papermaking fibers by conventional papermaking techniques and are useful for sanitary paper products such as towels and other wiper products.
2. Brief Description of the Prior Art
A strong trend exists in the paper industry to develop disposable products from papermaking fibers to serve as substitutes for conventional cloth products which are used as wipers and towels in both the home and industrial shops. To successfully gain consumer acceptance of these paper products, they must closely simulate cloth in both consumer perception and in performance. Thus, certain physical properties must be present in a successful product. Among these properties are softness, strength, stretchability, absorbency, ability to wipe dry, and bulk. Bulk is particularly important not only because it enables the paper product to feel like cloth, but also because it favorably interrelates with other desirable properties, such as softness and absorbency. And, of course, absorbency is very important where the product is to be used to wipe up spills.
Probably the most commonly employed method to produce a wiperlike paper product having the desirable bulk and absorbency is to laminate two or more embossed conventional paper webs together. One such method which has been found particularly advantageous is disclosed in U.S. Pat. No. Re 27,453. The "27,453 method" employs a pair of meshed embossing rolls which mechanically work two webs passed through the nip formed by the two rolls to produce crests and depressions in the webs and join them together by mechanical working of the webs at locations intermediate the crests and depressions. The "27,453 method" offers many advantages, one of which is an efficient web joining process due to the web working being performed on the sides of the embossing knuckles and involving shearing action in addition to compression against the webs. Another advantage is that the shearing action can be employed to perforate the webs and thus increase stretch and softness due to flexibility of the product. One disadvantage in the "27,453 method" is that the two webs are nested together as a result of being embossed together without spaces between the two webs. The addition of spaces between two webs would be beneficial because it creates additional bulk and absorbency in the product, as well as increased softness due to compressibility.
There are methods of laminating two or more webs together which avoid nesting the two webs together. In those methods, the two webs are embossed separately to produce crests and depressions on the webs and then brought together after applying adhesive to the crests on at least one of the webs. The two webs are joined together in a non-nested manner, which provides spaces between the two webs to increase the absorbency and bulk of the product.
In one such example of the prior art, disclosed in U.S. Pat. No. 3,414,459, the crests of each web on the sides facing each other are joined together with an adhesive. In another example of the prior art, disclosed in U.S. Pat. No. 3,556,907, the embossed configuration of each web is different from the other web, and the crests on one web are joined with adhesive to the depressions of the other web. In yet another example of the prior art, disclosed in U.S. Pat. No. 3,708,366, the height of the crests of the first web is greater than the height of the crests on the second web, and the higher crests on the first web are joined with adhesive to the depressions on the second web.
All of the prior art examples of two-ply laminated webs where the webs are embossed before being joined together generally require the use of adhesive, which results in a harsher product, a more complex process, and additional expense. There is some suggestion in the prior art that the webs can be joined by the application of moisture and pressure to the webs at their crests to compress the webs together, but such pressure would have to be excessive to provide satisfactory joining strength, if even possible. On the other hand, the "27,453 method", while avoiding the described disadvantages of the other plying methods, does not create the amount of bulk and absorbency in the product which can be created in the non-nested products. Practice of the present invention combines the advantages of the joining technique and increased stretch and softness due to flexibility of the "27,453 method" with the increased bulk and absorbency and softness due to compressibility of the non-nested two-ply prior art methods.
The invention is a two-ply, non-nested, fibrous sheet material made preferably from papermaking fibers and which consists of two webs joined together with inner surfaces facing each other. Each web has a plurality of crests and depressions on its inner surface. The crests on each web are positioned between the crests on the other web and extend beyond the crests of the other web toward but spaced from the depressions on the other web to form spaces between the two webs. The two webs are connected to each other at locations intermediate the crests and depressions on at least one of the webs, and preferably on both. In the preferred embodiment the webs are connected to each other by mechanically welding in a manner which perforates the webs at the joining locations. The perforations permit additional stretch in the sheet material, and by controlling the alignment of the perforations, stretch can be increased in web directions such as the cross-machine direction where most paper webs have little stretch.
The invention also consists of a method for forming the above-described two-ply sheet material by the steps of separately embossing each of the two webs to form a plurality of crests and depressions on the inner side of each web, bringing the two webs together to position the crests on the inner side of each web between the crests on the inner side of the other web with the crests on each web extending beyond the crests on the other web toward but spaced from the depressions on the other web, and connecting the two webs to each other at locations intermediate the crests and depressions on at least one of the webs, and preferably on both. In the preferred method, the webs are connected to each other by mechanical welding in a manner which creates perforations in the sheet material at the locations where the webs connect to each other.
The invention also consists of an apparatus for performing the above-described method and which consists of two rotatably mounted embossing rolls, each having outwardly extending embossing knuckles and at least one of the embossing rolls having outwardly tapering knuckles. The embossing rolls are positioned with respect to each other to cause contact of successive embossing knuckles of one of the embossing rolls with successive embossing knuckles of the other embossing roll at locations along the sides of the embossing knuckles. The embossing rolls are further arranged with respect to each other to maintain a space between the top of each knuckle and the base of the knuckles meshed with it on the other embossing roll. The apparatus further includes an elastomer covered press roll in nipping relationship with each of the embossing rolls for pressing a web against each embossing roll to contour the web to the knuckle configuration of that embossing roll.
FIG. 1 is a schematic elevation view of the apparatus of the invention producing the product of the invention.
FIG. 2 is an enlarged sectional elevation view taken from FIG. 1 showing the preferred form of the product of the invention.
FIG. 3 is an enlarged sectional plan view taken along line 3--3 of FIG. 1.
FIG. 4 is an enlarged sectional elevation view of the apparatus of the invention taken along line 4--4 of FIG. 1 (the webs are not shown).
FIG. 1 illustrates the apparatus of the invention. It consists of upper embossing roll 11, lower embossing roll 12, upper press roll 13 and lower press roll 14, each rotatably mounted and driven by conventional means not shown. Each of the press rolls are in nipping relationship with its respective embossing roll. The embossing rolls 11 and 12 have embossing knuckles 17 and 18 extending outwardly from their circular periphery, and the press rolls 13 and 14 each have an elastomer cylindrical cover. The embossing rolls 11 and 12 are positioned with respect to each other through gears or other conventional means not shown to mesh knuckles 17 on upper embossing roll 11 with knuckles 18 on lower embossing roll 12.
A first fibrous web 15 is shown passing through the nip formed by upper embossing roll 11 and upper press roll 13 where the web is pressed against and conformed to the configuration of the knuckles 17. The web 15 then continues in rotation with upper embossing roll 11 to the nip formed by the two embossing rolls 11 and 12. A second fibrous web 16 is passed through the nip formed by lower embossing roll 12 and lower press roll 14 where it is pressed against and conformed to the configuration of the knuckles 18. The fibrous web 16 then continues in rotation with lower embossing roll 12 to the nip formed by the two embossing rolls 11 and 12. At the nip formed by the embossing rolls 11 and 12, knuckles 17 and 18 are positioned with respect to each other to mesh as illustrated in FIGS. 3 and 4, where they are illustrated contacting each other at locations on their sides between their crests and depressions. The contact between knuckles 17 and 18 is made with sufficient force to mechanically work the two webs 15 and 16 together and join them. The two webs 15 and 16 are joined together by the intermeshing knuckles into a two-ply sheet material 19, and pulled from the embossing rolls 11 and 12 by conventional means not illustrated.
The two-ply sheet material 19 is the product of the invention and is more clearly illustrated in FIG. 2 where the first web 15 displays on its inner surface crests 21 and depressions 28, and the second web 16 also displays on its inner surface crests 29 and depressions 22. The two webs 15 and 16 are connected to each other at locations 20 intermediate the crests and depressions of both webs. The crests 21 of web 15 are spaced from the depressions 22 of web 16, and the crests 29 of web 16 are spaced from the depressions 28 of web 15. Thus, spaces are provided between the two webs 15 and 16 to increase absorptive capacity and product bulk, as well as softness due to compressibility.
The webs 15 and 16 are joined together by mechanical welding, which consists of pressing selected portions of the webs together and working those portions through movement of one knuckle against another with sufficient pressure to intermesh the fibers of one web with the fibers of the other webs so that the two webs are held together. The degree to which the two webs 15 and 16 are mechanically joined together is governed by the configuration of the embossing knuckles 17 and 18 and the amount of nip pressure between the two embossing rolls 11 and 12. By applying sufficient nip pressure, the webs 15 and 16 can be perforated by the intermeshing knuckles in addition to being joined together. Perforating the webs increases flexibility or softness of the web and also increases extensibility of the web, an advantage which is particularly useful when it is in the cross-machine direction of the web. U.S. Pat. No. Re 27,453, which is hereby incorporated by reference into the specification, discloses advantages of perforating the web in this manner.
The embossing knuckles 17 and 18 are more clearly illustrated in FIGS. 3 and 4. The interference of the embossing knuckles 17 and 18 with each other is clearly shown in FIG. 4 where the distal ends 25 of embossing knuckles 17 extend beyond distal ends 23 of embossing knuckles 18. The knuckles 17 and 18 are tapered outwardly (the sides converge in the outward direction) to permit contact with each other at their sides 27. The knuckles 17 and 18 illustrated in FIG. 4 each have an equally-sloped straight-line taper along their contact sides 27, causing mechanical welding of the two webs over relatively large areas of the locations 20 where the webs join together. However, the contact sides 27 of the knuckles 17 and 18 could be convexly curved if smaller areas of the locations 20 where the webs join together were desired. It is readily apparent that the depth to which distal ends 23 or 25 of embossing knuckles on one embossing roll extend beyond the distal ends 23 or 25 of embossing knuckles on the other embossing roll and thus the size of the spaces between webs 15 and 16 in product 19, can be regulated by the shape of each embossing knuckle 17 and 18. This depth is referred to as the degree of interference, with 100% meaning that the distal ends 23 and 25 contact the depressions 24 and 26 on the other embossing roll.
FIG. 3 illustrates knuckles 17 of upper embossing roll 11 overlapping in the machine direction (direction of roll rotation) knuckles 18 of lower embossing roll 12. The mechanical working of the webs 15 and 16 which causes welding of the webs to each other and creates perforations in the webs, if desired, is confined to the areas of overlap of the knuckles 17 and 18. Thus, the amount of overlap offers one control on the size of the perforations, with greater overlap producing longer perforations in the machine direction. By making the perforations longer in the machine direction than they are in the cross-machine direction, the product has a greater increase in stretch and flexibility in the cross-machine direction than in the machine direction. Still referring to FIG. 3, the knuckles 17 and 18 on both embossing rolls 11 and 12 are illustrated as being arranged in rows which are diagonally disposed with respect to the embossing roll axis. This arrangement has been found to produce the preferred product having diagonally disposed rows of crests, but the knuckles could also be arranged in axially aligned rows with good results.
Referring back to FIG. 2, the preferred form of product 19 is one of fibrous webs 15 and 16 which were formed by deposition of an aqueous slurry of lignocellulosic fibers, although webs of other natural and synthetic fibers, formed from aqueous slurries or dry formed, could be used. Each web 15 and 16 preferably has a basis weight of from about 10 to about 30 pounds per ream of 2,880 square feet. The preferred form of the product 19 is also one which has from about 70 to about 300 crests or embossed areas per square inch on each side of the product 19 and perforations in the webs at joining locations 20 which extend in the machine direction of the webs from about 0.010 inch to about 0.100 inch. The number of perforations is preferably from about 140 to about 600, there being one on each side of each crest. The preferred spacing of the crests 21 or 29 on one web from the depressions 22 or 28 on the other web is from about 10% to about 70% of the bulk thickness of the product 19. Producing this spacing requires knuckle interference of from about 30 % to about 90%. The preferred finished sheet material will have a bulk thickness of from about 0.010 inch to about 0.050 inch.
To further illustrate a preferred form of the invention, the following example is given. Two paper webs were formed by conventional papermaking techniques from a pulp slurry of 50% bleached sulfate softwood and 50% bleached sulfate hardwood. The two webs were identical to each other and each had the following physical properties:
Tensile Strength MD 40.5oz./in.Stretch MD 22.1%Tensile Strength CD 21.5oz./inStretch CD 4.6%Bulk .080in/24 sheetsBasis Weight 14.4lbs/2880ft.2Absorbency (1cc of H2 O) 418 seconds
The two webs were passed through the apparatus of the invention having the following specifications. The embossing rolls were made from hardened steel and had a diameter of 8 inches and embossing knuckles about the periphery at a concentration of 128 per square inch and of a size of .0325 inch × .090 inch, with the longer dimension extending circumferentially about the roll. The depth of each embossing knuckle from distal end to depression was .021 inches, and they were set to interfere with each other to a depth of .015 inches. The embossing knuckles tapered outwardly in a straight taper at equal slopes on both embossing rolls. The press rolls each had an overall diameter of 4.5 inches, including a 1/4 inch thick rubber cover having a hardness of 45 durometer. The nip loading of each press roll with its embossing roll was set at 120 pounds per linear inch. The two webs were passed through the embossing rolls at a speed of 50 fpm. The physical properties of the finished two-ply web product were the following:
Tensile Strength MD 52.3oz./in.Stretch MD 11.8%Tensile Strength CD 16.0oz./in.Stretch CD 13.7%Bulk .429 in/24 sheetsBasis Weight 26.5lbs/2880ft2Absorbency (1cc H2 O) 1.8 second
The preferred forms of the invention have been described, but it should be recognized that variations may be practiced with many of the advantages of the preferred forms. One example is the use of knuckles which contact only one knuckle on the other embossing roll, joining the webs only on one side of the crests. Another example is the use of knuckles on one embossing roll which do not taper outwardly, joining the edge of the crests of one web to areas on the other web intermediate the crests and depressions. And another example is the use of an adhesive to replace or supplement the mechanical welding of the web. Also, one or more additional webs could be passed through the embossing rolls either along with the first or second webs through the nip formed by a press roll or by avoiding the press rolls.
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US3414459 *||1 Feb 1965||3 Dic 1968||Procter & Gamble||Compressible laminated paper structure|
|US3556907 *||23 Ene 1969||19 Ene 1971||Paper Converting Machine Co||Machine for producing laminated embossed webs|
|US3708366 *||25 Nov 1970||2 Ene 1973||Kimberly Clark Co||Method of producing absorbent paper toweling material|
|US3738905 *||29 Abr 1970||12 Jun 1973||Kimberly Clark Co||Paper toweling material and method of combining into multi ply products|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US4100017 *||20 Sep 1976||11 Jul 1978||The Procter & Gamble Company||Multi-ply tissue product|
|US4228851 *||12 Ago 1977||21 Oct 1980||Aluminum Company Of America||Solar heating panel|
|US4325768 *||14 Dic 1979||20 Abr 1982||American Can Company||Method of manufacturing fibrous sheet structure|
|US4325773 *||14 Dic 1979||20 Abr 1982||American Can Company||Apparatus for manufacturing fibrous sheet structure|
|US4326002 *||15 May 1980||20 Abr 1982||American Can Company||Multi-ply fibrous sheet structure and its manufacture|
|US4671983 *||12 Jun 1985||9 Jun 1987||Marcal Paper Mills, Inc.||Embossments for minimizing nesting in roll material|
|US4942889 *||6 Feb 1986||24 Jul 1990||Philip Morris Incorporated||Expanded web of sheet material and method of making same|
|US5061232 *||12 Abr 1989||29 Oct 1991||Scott Paper Company||Rolled paper embossing dispenser|
|US5269983 *||9 Ene 1992||14 Dic 1993||James River Corporation Of Virginia||Rubber-to-steel mated embossing|
|US5294475 *||12 Jun 1992||15 Mar 1994||The Procter & Gamble Company||Dual ply cellulosic fibrous structure laminate|
|US5356506 *||4 Abr 1994||18 Oct 1994||The Procter & Gamble Company||Modular construction pattern rolls for use in paper converting|
|US5366785 *||1 Oct 1993||22 Nov 1994||The Procter & Gamble Company||Cellulosic fibrous structures having pressure differential induced protuberances and a process of making such cellulosic fibrous structures|
|US5458950 *||29 Mar 1993||17 Oct 1995||The James River Corporation||Paper towel with dual level diagonal infundibulate striae of slitted elongate hexagonal bosses|
|US5468323 *||15 Nov 1993||21 Nov 1995||The Procter & Gamble Company||Apparatus and process for making a dual ply cellulosic fibrous laminate|
|US5520778 *||9 Ago 1994||28 May 1996||The Procter & Gamble Company||Cellulosic fibrous structures having pressure differential induced protuberances and a process of making such cellulosic fibrous structures|
|US5562805 *||18 Feb 1994||8 Oct 1996||Kimberly-Clark Corporation||Method for making soft high bulk tissue|
|US5635275 *||5 Ago 1994||3 Jun 1997||Tredegar Industries, Inc.||Lamination of non-apertured three-dimensional films to apertured three-dimensional films and articles produced therefrom|
|US5635276 *||6 Jun 1995||3 Jun 1997||Tredegar Industries, Inc.||Lamination of non-apertured three-dimensional films to apertured three-dimensional films and articles produced therefrom|
|US5693403 *||27 Mar 1995||2 Dic 1997||Kimberly-Clark Worldwide, Inc.||Embossing with reduced element height|
|US5698054 *||6 Jun 1995||16 Dic 1997||Tredegar Industries, Inc.||Method and apparatus for the lamination of apertured or non-apertured three-dimensional films to apertured or non-apertured three-dimensional and/or flat films|
|US5702571 *||13 May 1996||30 Dic 1997||Kimberly-Clark Worldwide, Inc.||Soft high bulk tissue|
|US5783014 *||3 Sep 1996||21 Jul 1998||Tredegar Industries, Inc.||Lamination of apertured or non-apertured three-dimensional films to apertured or non-apertured three-dimensional and/or flat films|
|US5861081 *||7 Jun 1995||19 Ene 1999||James River Corporation Of Virginia||Paper towel with dual level diagonal infundibulate striae of slitted elongate hexagonal bosses|
|US5900114 *||3 Jul 1997||4 May 1999||Kimberly-Clark Worldwide, Inc.||Embossing with reduced element height|
|US6106929 *||17 May 1999||22 Ago 2000||Fort James Corporation||Paper towel with dual level diagonal infundibulate striae of slitted elongate hexagonal bosses|
|US6165585 *||19 Sep 1997||26 Dic 2000||The Procter & Gamble Company||Laminated fibrous structure and method for manufacturing same|
|US6602577||3 Oct 2000||5 Ago 2003||The Procter & Gamble Company||Embossed cellulosic fibrous structure|
|US6649025||31 Dic 2001||18 Nov 2003||Kimberly-Clark Worldwide, Inc.||Multiple ply paper wiping product having a soft side and a textured side|
|US6733626 *||21 Dic 2001||11 May 2004||Georgia Pacific Corporation||Apparatus and method for degrading a web in the machine direction while preserving cross-machine direction strength|
|US6887349||5 Sep 2002||3 May 2005||Fort James Corporation||Apparatus and method for degrading a web in the machine direction while preserving cross-machine direction strength|
|US6913673||19 Dic 2001||5 Jul 2005||Kimberly-Clark Worldwide, Inc.||Heated embossing and ply attachment|
|US6966971||26 Abr 2002||22 Nov 2005||Sellars Absorbent Materials, Inc.||Absorbent wipe having bonding material logo|
|US7037406 *||6 Ago 2003||2 May 2006||Fort James Corporation||Cross-machine direction embossing of absorbent paper products having an undulatory structure including ridges extending in the machine direction|
|US7118796||3 Dic 2004||10 Oct 2006||Fort James Corporation||Multi-ply absorbent paper product having impressed pattern|
|US7182838 *||25 Mar 2004||27 Feb 2007||Georgia Pacific Corporation||Apparatus and method for degrading a web in the machine direction while preserving cross-machine direction strength|
|US7297226||11 Feb 2004||20 Nov 2007||Georgia-Pacific Consumer Products Lp|
|US7326322 *||12 Nov 2004||5 Feb 2008||Georgia Pacific Consumer Products Lp|
|US7338038 *||12 Mar 2004||4 Mar 2008||Dow Global Technologies, Inc.||Impact absorption structure|
|US7431975||29 Nov 2002||7 Oct 2008||Dzs, L.L.C.||Textured composite material|
|US7497923||27 Ago 2004||3 Mar 2009||Kimberly-Clark Worldwide, Inc.||Enhanced multi-ply tissue products|
|US7678230||15 Dic 2006||16 Mar 2010||Kimberly-Clark Worldwide, Inc.||Environmentally sustainable multiple ply paper product|
|US7699959||2 Mar 2009||20 Abr 2010||Kimberly-Clark Worldwide, Inc.||Enhanced multi-ply tissue products|
|US7799176||8 Oct 2007||21 Sep 2010||Georgia-Pacific Consumer Products Lp|
|US7857941||18 Dic 2006||28 Dic 2010||Georgia-Pacific Consumer Products Lp|
|US7862686||19 Feb 2010||4 Ene 2011||Kimberly-Clark Worldwide, Inc.||Enhanced multi-ply tissue products|
|US7927457||19 Abr 2011||Kimberly-Clark Worldwide, Inc.||Environmentally sustainable multiple ply paper product|
|US8142617||23 Ago 2010||27 Mar 2012||Georgia-Pacific Consumer Products Lp|
|US8158047||17 Abr 2012||Georgia-Pacific Consumer Products Lp||Multi-ply absorbent paper product having impressed pattern|
|US8178025||15 May 2012||Georgia-Pacific Consumer Products Lp||Embossing system and product made thereby with both perforate bosses in the cross machine direction and a macro pattern|
|US8287694||16 Oct 2012||Georgia-Pacific Consumer Products Lp|
|US8414738||30 Ago 2007||9 Abr 2013||Kimberly-Clark Worldwide, Inc.||Multiple ply paper product with improved ply attachment and environmental sustainability|
|US8535481||13 Jun 2012||17 Sep 2013||Georgia-Pacific Consumer Products Lp|
|US8647105||16 Abr 2012||11 Feb 2014||Georgia-Pacific Consumer Products Lp||Embossing system and product made thereby with both perforate bosses in the cross machine direction and a macro pattern|
|US8726424||3 Jun 2010||20 May 2014||Intellectual Property Holdings, Llc||Energy management structure|
|US9271879 *||11 Mar 2010||1 Mar 2016||The Procter & Gamble Company||Article having a seal and process for forming the same|
|US9320311||14 Mar 2013||26 Abr 2016||Intellectual Property Holdings, Llc||Helmet impact liner system|
|US20030138597 *||21 Dic 2001||24 Jul 2003||Ruthven Paul J.|
|US20040055694 *||6 Ago 2003||25 Mar 2004||Kershaw Thomas N.||Cross-machine direction embossing of absorbent paper products having an undulatory structure including ridges extending in the machine direction|
|US20040106345 *||29 Nov 2002||3 Jun 2004||Zafiroglu Dimitri Peter||Textured composite material|
|US20040180178 *||25 Mar 2004||16 Sep 2004||Georgia Pacific Corporation|
|US20050022955 *||27 Ago 2004||3 Feb 2005||Margaret M. Ward||Enhanced multi-ply tissue products|
|US20050092195 *||12 Nov 2004||5 May 2005||Fort James Corporation|
|US20050098281 *||3 Dic 2004||12 May 2005||Fort James Corporation||Multi-ply absorbent paper product having impressed pattern|
|US20050173085 *||11 Feb 2004||11 Ago 2005||Schulz Galyn A.|
|US20050200062 *||12 Mar 2004||15 Sep 2005||Dow Global Technologies, Inc.||Impact absorption structure|
|US20050241788 *||1 Jul 2005||3 Nov 2005||Baggot James L||Heated embossing and ply attachment|
|US20060118993 *||3 Dic 2004||8 Jun 2006||Fort James Corporation||Embossing system and product made thereby with both perforate bosses in the cross machine direction and a macro pattern|
|US20070144693 *||18 Dic 2006||28 Jun 2007||Georgia Pacific Corporation|
|US20080066882 *||8 Oct 2007||20 Mar 2008||Georgia-Pacific Consumer Products Lp||Apparatus and Method for Degrading a Web in the Machine Direction While Preserving Cross-Machine Direction Strength|
|US20080142177 *||15 Dic 2006||19 Jun 2008||Thomas Gerard Shannon||Environmentally sustainable multiple ply paper product|
|US20090162611 *||2 Mar 2009||25 Jun 2009||Ward Margaret M||Enhanced Multi-Ply Tissue Products|
|US20100043989 *||30 Oct 2009||25 Feb 2010||Kimberly-Clark Worldwide, Inc.||Environmentally Sustainable Multiple Ply Paper Product|
|US20100233428 *||11 Mar 2010||16 Sep 2010||Keith Joseph Stone||Article having a seal and process for forming the same|
|US20100307704 *||17 Ago 2010||9 Dic 2010||Georgia-Pacific Consumer Products Lp|
|US20110042024 *||23 Ago 2010||24 Feb 2011||Georgia-Pacific Consumer Products Lp|
|USD430734||7 Ago 1998||12 Sep 2000||Fort James Corporation||Pattern for an embossed paper product|
|USD436738||7 Ago 1998||30 Ene 2001||Fort James Corporation||Embossed paper product|
|USD440051||7 Ago 1998||10 Abr 2001||Fort James Corporation||Paper towel|
|USD443766||21 Jul 2000||19 Jun 2001||Fort James Corporation||Pattern for an embossed paper product|
|USD459897||25 Jul 2000||9 Jul 2002||Fort James Corporation||Paper towel|
|USD679058||26 Mar 2013||Intellectual Property Holdings, Llc||Helmet liner|
|USD683079||21 May 2013||Intellectual Property Holdings, Llc||Helmet liner|
|USD733972||12 Sep 2013||7 Jul 2015||Intellectual Property Holdings, Llc||Helmet|
|EP0162704A2 *||21 May 1985||27 Nov 1985||Philip Morris Products Inc.||Manufacture of an expanded web of sheet material|
|EP0408248A2 *||5 Jul 1990||16 Ene 1991||James River Corporation Of Virginia||Embossing and laminating apparatus for paper|
|EP1096069A2 *||1 Nov 2000||2 May 2001||Fort James Corporation||Multi-ply absorbent paper product having impressed pattern|
|EP1321287A2 *||19 Dic 2002||25 Jun 2003||Fort James Corporation||An embossing apparatus and method for degrading a web in the machine direction while preserving cross-machine direction strength|
|EP1321287A3 *||19 Dic 2002||24 Sep 2003||Fort James Corporation||An embossing apparatus and method for degrading a web in the machine direction while preserving cross-machine direction strength|
|Clasificación de EE.UU.||428/178, 101/32, 156/210, 162/112, 428/184, 162/117, 428/180|
|Clasificación internacional||B32B38/04, B32B38/06, B31F1/07, B29C67/20, D21H27/40|
|Clasificación cooperativa||Y10T428/24711, Y10T156/1025, B31F2201/0728, B31F2201/0797, B31F1/07, Y10T428/24661, B31F2201/0764, B31F2201/0738, B32B38/06, D21H27/40, B31F2201/0756, B29C67/20, B31F2201/0733, B31F2201/0761, Y10T428/24678|
|Clasificación europea||B31F1/07, D21H27/40, B32B38/06|