|Publication number||US3821163 A|
|Publication date||Jun 28, 1974|
|Filing date||Aug 6, 1973|
|Priority date||Aug 30, 1971|
|Publication number||US 3821163 A, US 3821163A, US-A-3821163, US3821163 A, US3821163A|
|Original Assignee||Ciba Geigy Corp|
|Export Citation||BiBTeX, EndNote, RefMan|
|Referenced by (22), Classifications (8)|
|External Links: USPTO, USPTO Assignment, Espacenet|
United States Patent [-191 Spivack June 28, 1974 1 METAL COMPLEXES OF  References Cited N,N'-DIALKYLESTERS OF UNITED STATES PATENTS ETHYLENEDINITRILO'TETRAACETIC 2,327,517 8/1943 Frolick et a1. 260/45.85 ACID: STABILIZERS FOR POLYMERS 2,724,706 11/1955 Bersworth 260/45.75 2,859,104 11/1958 Kroll 260/429 [75 1 lnvemor' 32" Sp'mg Valley 3,051,563 8/1962 Bersworth 260/429 3,102,107 8/1963 Soeder 260/4575 Assignge: Ciba Geigy Corporation 1 Luciani Ct a1 Greenburgh, 3,497,535 2/1970 Lennon 260/429 1 Filed: 6, 1973 Primary Examiner-Donald E. Czaja  APPL 385,790 Assistant ExaminerV. P. Hoke Related U.S. AppllCaliml Data 57 ABSTRACT  gy g g g gg 32 Synthetic polymeric compositions which are subject to ultraviolet light deterioration are stabilized by means of an effective amount of a metal complex of N,Nal-'  g ghg i z kyl esters of ethylenedinitrilotetraacetic acid. Poly- 260/45 75 k 260/45 i meric compositions containing these stabilizers also  Int Cl C08f45/6i C08 /62 exhibit an increase in susceptibility to dye as com-  Fieid 45 75 R 4585 Ng398 5 pared to the unstabilized polymeric compositions. A
260/4575 N, 45.75 C; 99/163; 252/47, 51.5 R, 401', 8/172 typical embodiment is the nickel complex, N,N-di-noctadecyl ester of ethyleriedinitrilotetraacetic acid.
10 Claims, N0 Drawings 1 METAL COMPLEXES OF N,N'-DIALKYLESTERS OF ETHYLENEDINlTRlLO-TETRAACETIC ACID: STABILIZERS FOR POLYMERS CROSS REFERENCE This is a continuation-in-part of a copending application Ser. No. 176,307, filed Aug. 30. now U S.v Pat. No. 3,751,440 issued Aug. 7, 1973. DETAILED DISCLOSURE The present invention relates to novel metal derivatives of N, N'-dialkyl esters of ethylenedinitrilo tetraacetic acid and the use thereof in the preparation of synthetic polymeric compositions of increased stability to ultraviolet (UV) light and increased susceptibility to dye.
More specifically, this invention relates to a compound of the formula:
wherein R is an alkyl group of from 1 to 22 carbon atoms;
M is selected from the group consisting ofzinc, manganese, nickel, cobalt, chromium, copper, aluminum, titanium and iron, and n has a value of from 1 to 4, the value of n being the same as the available valence of M.
By the term alkyl is intended a branched or straight chain saturated hydrocarbon group having from one to 22 carbon atoms. Typical of such alkyl groups are methyl, ethyl, propyl, isopropyl, butyl, t-butyl, pentyl, isopentyl, hexyl, octyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, docosyl and the like.
The group M consists of a metal cation such as the cation form of lithium, sodium, potassium, barium, calcium, aluminum, titanium, tin, vanadium, antimony, chromium, molybdenum, maganese, iron, cobalt, copper and the like, that is, a metal having an atomic number of up to 56. The preferred metal cations are zinc, manganese, nickel, cobalt, chromium, copper, aluminum, titanium and iron. The most preferred is nickel.
This invention also relates to compositions of matter which are stabilized against ultraviolet deterioration which comprises a synthetic organic polymer normally subject to ultraviolet deterioration containing from about 0.05% to percent by weight of the polymer of the compounds of formula 1 and preferably from 0.2 percent to 5 percent by weight.
The compounds of the present invention also render synthetic polymeric substances, such as the poly-aolefms of the polyethylene and polypropylene type, more amenable to dyeing and also reduce the tendency of the polymeric substance to discolor and embrittle upon exposure to light, whether dyed or not. These compounds may be incorporated in the polymeric substance duringthe usual processing operations, for example by hot milling, the composition then being extruded, pressed, blow molded or the like into films, fi-
bers, filaments, hollow shapes and the like. Moreover, polymeric compositions containing these novel salts may be dyed, either directly after incorporation of the salt or after further processing, such as the formation of yarns or fabrics. The polymer is stabilized by the presence of these metal salts both before and after dyeing so that the coloring step need not follow directly. Once dyed, the colored compositions exhibit fastness to light and to solvents, properties preferred in washing, dry cleaning and general use.
The conditions of the dyeing will of course vary with the particular dye employed. Generally the nature of the dye is not restricted and any of the many known metal chelating dyes may be employed, as for example. the orange dye of the formula:
It is also to be understood that the effect obtained with a particular dye can be altered by variation of the particular metal cation of these compounds and by the amount of these compounds present in the polymer, although generally from about 0.05 to 10 percent preferably 0.1 to 5 percent by weight, is employed.
While polypropylene has been herein mentiond specifically, these compounds are useful in numerous other substances whose regular and inert polymeric structures tend to resist dyes and are subject to UV deterioration. Materials for which the compounds of the present invention are useful thus include synthetic organic polymeric substances, both homopolymeric and copolymeric, such as vinyl resins formed from the polymerization of vinyl halides or from the copolymerization of vinyl halides with unsaturated polymerizable compounds, e.g., vinyl ester, a, B-unsaturated acids. 0:. B-unsaturated esters, a, B-unsaturated ketones, a, B-unsaturated aldehydes and unsaturated hydrocarbons such as butadienes and styrene; poly-a-olefms such as polyethylene, polypropylene, polybutylene, polyisoprene and the like, including copolymers of poly-a-olefins; polyurethanes such as are prepared from polyols and organic polyisocyanates; polyamides, such as polyhexamethylene adipamide; polyesters such as polymethylene terephthalates; polycarbonates; polyacetals; polystyrene; polyethyleneoxide; polyacrylics such as polyacrylonitrile; and the like, including mixtures of the foregoing such as those of high impact polystyrene containing copolymers of butadiene and styrene and those formed by the copolymerization of acrylonitrile, butadiene and/or styrene. The compounds of this invention may be used for stabilizing the above materials even when dyeing is not anticipated.
Other materials which while not generally dyed, are
nevertheless stabilized against UV deterioration by the compounds of the present invention include lubricating oil of the aliphatic ester type, e.g., di-( Z-ethylhexyl) azelate, pentaerythritol tetracaproate and the like; animal and vegetable derived oils, e.g., linseed oil, fat, tallow, lard, peanut oil, cod liver oil, castor oil, palm oil, cotton seed oil and the like; hydrocarbon material such as gasoline, both natural and synthetic, diesel oil, mineral oil, fuel oil, cutting fluids, waxes, resins and the like; fatty acids; varnishes, soaps; and the like.
The stabilizers employed in this invention can be also used in combination with other stabilizers or additives. There may also be present compounds which help to improve the heat and oxidative stability of polymers such as phenolic compounds which inactivate free radicals, by hydrogen atom donation, as well as, compounds capable of decomposing peroxides such as dilaurylthiodipropionate. The stabilizers may also be used in combination with other additives such as UV light absorbers, antiacids such as calcium soaps, phosphates, anti-static agents, and the like. Other materials which may also be incorporated into the polymer composition include for examples, pigments, dyes, fillers, etc.
The stabilized polymers of the present invention have utility in the normal uses for which plastics are employed and are particularly useful for film, coatings and fiber.
The compounds of the present invention per se, can be prepared by treating the appropriate dialkyl ester of ethylenedinitrilotetraacetic acid with the reactive form of the metal or complex, e.g., sodium hydroxide, lithium hydroxide, potassium hydroxide or the like. Alter natively, and preferably in the case of metal complexes and metals other than alkali metals, a double decomposition is employed. Thus, for example, a sodium salt of the present invention is treated with nickel chloride. In a similar fashion, use of other halides such as aluminum chloride, barium, chloride and the like results in formation of the corresponding metal derivative.
The preparation of the N, N'-dialkyl esters of ethylenedinitrilotetraacetic acid that are used as starting materials in preparing the compounds of this inventions are described in US. Pat. No. 3,497,535. The N,N'- dialkyl esters of ethylenedinitrilotetraacetic acid, can conveniently be prepared by the reaction of ethylenedinitrilotetraacetic acid dianhydride and suitable alcohols.
The following examples, presented for illustration and not limitation, will serve to typify the nature of the present invention.
EXAMPLE 1 Nickel Complex of N,N'-Di-n-octadecyl ester of Ethylenedinitrilotetraacetic Acid A solution of l 1.16 grams of the di-n-octadecyl ester of ethylenedinitrilo tetraacetic acid (0.014 mole) in l liter of isopropanol was converted to a solution of the dipotassium salt by the addition of 28.0 ml of l normal methanolic potassium hydroxide. To this solution was added 3.32 grams of nickel chloride hexahydrate (0.0M mole) at a temperature of l0C. The turbid reaction mixture was stirred at 23 to 25C for 2 and V2 hours and at 50C for 20 minutes. The reaction mixture was then clarified by filtration, the clear filtrate being concentrated by distillation at 45C and 15 mm mercury. The isolated residue was dissolved in 100 ml benzene, filtered, and the residue isolated by distillation of the solvent at 4045C at a pressure of 0.10 mm Hg. for 3 hours.
Analysis Nickel 7:
Calculated 6.88 Found 6.45
By following the above procedure and substituting the N,N'-dimethyl ester of ethylenedinitrilotetraacetic acid for the N,N'-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid there is thus obtained the nickel complex of N,N'-dimehtyl ester of ethylenedinitrilotetraacetic acid.
EXAMPLE 2 By following the procedure of Example 1 and substituting the following metal complexes for nickel chloride,
a. Manganese chloride b. Zinc chloride c. Cobalt chloride (1. Chromium chloride e. Copper chloride f. Aluminum chloride g. Titanium chloride h. Ferric chloride There are thus respectively obtained:
a. Manganese complex of N,N'-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
b. Zinc complex of N,N'-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
c. Cobalt complex of N,N'-di-n-octadecylester of vethylenedinitrilotetraacetic acid.
d. Chromium complex of N,N-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
e. Copper complex of N,N'-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
f. Aluminum complex of N,N'-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
g. Titanium complex of N,N'-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
h. Iron complex of N,N-di-n-octadecyl ester of ethylenedinitrilotetraacetic acid.
EXAMPLE 3 Ethylenedinitrilotetraacetic Acid, N,N'-di-n-butyl Ester 600 ml. of n-butanol was dried by azeotropic distillation of 140 ml. of the charged n-butanol. 60 grams of ethylenedinitrilotetraacetic acid dianhydride was added to the dried n-butanol at C. The heterogeneousreaction mixture was then heated at reflux for two and one half hours yielding a clear solution. The reaction mixture was concentrated to dryness at an initial pressure of 15 mm Hg. and finally at oil pump pressure of about 0.5 mm Hg. The crystallineresidue was triturated several times with cold petroleum ether. The insoluble crystalline product was then filtered and dried yielding white crystals melting at 68-7 1C.
EXAMPLE 4 Nickel Complex of Ethylenedinitrilotetraacetic Acid. N,N'-di-n-butyl Ester 135 grams of ethylencdinitrilotetraacetic acid, N,N- di-n-butyl ester (0.034 mole) is neutralized with 34.0 ml of 2.00 N aqueous sodium hydroxide at room temperature to yield a clear solution. 8.06 grams of nickel chloride hexahydrate dissolved in ml of water was added dropwise. After one third of the nickel chloride solution was added it was necessary to dilute the resulting thick slurry with 50 ml of water. The remainder of the nickel chloride was added and the reaction mixture stirred for three hours. The resulting light blue precipitate was filtered, the filter-cake being reslurried with small portions of cold water until almost all the sodium chloride had been removed. The precipitate was dried in the vacuum dessicator over calcium sulfate at a final pressure of 0.10 mm Hg. for 20 hours yielding 10.7 grams of a light blue solid, mp. 230240C.
Analysis 7r N 7: H O
Calculated 11.80 7.25 Found 11.99 6.58
Analysis indicates that the product is isolated mainly as the dihydrate.
EXAMPLE 5 v with 40 ml of 2.00 N sodium hydroxide and allowed to react with manganese dichloride tetrahydrate dissolved in ml of water. After washing the precipitate, and drying it at about 0.5 mm Hg. for 20 hours and finally at 0.1 mm Hg. for 20 hours, 14.7 grams of an off-white manganese complex is obtained which does not melt even at 340C.
Analysis 7: MN 7: H2O
Calculated 12.02 0.00
Found 11.83. 11.88 0.45. 0.24
EXAMPLE 6 Nickel Complex of Ethylenedinitrilotetraacetic Acid, N.N-di-n-dodecyl Ester A gelatinous dispersion of the sodium salt of ethylenedinitrilotctraacetic acid. N.N-didodecyl ester was made by reacting 13.95 grams of ethylenedinitrilotctraacctic acid. N,N'-didodecyl ester (0.022 mole) with 22 m1 of 2.00 normal aqueous sodium hydroxide in 500 ml of water. To this dispersion was added dropwise over 20 minutes 5.25 grams of nickel chloride hexahydrate (0.022 mole) dissolved in 20 ml of water. A blue precipitate formed immediately which was allowed to stir for 2 hours and then filtered and washed with cold water until substantially free of chloride ion. A second crop was obtained by concentrating the filtrate to one-third volume at 30C. under vacuum. The resulting precipitate was filtered and washed free of chloride ion as previously described. Both filter cakes were combined and dried in the vacuum dessicator at 0.1 mm Hg. for 24 hours at room temperature. The resulting light blue solid 13.6 g) melted at 245 to 250C to a clear melt.
Analysis shows that the product is isolated as the 1:1 nickel complex containing two moles of water of hydration.
EXAMPLE 7 Manganese Complex of Ethylenedinitrilotetraacetic Acid, N,N-di-n-d0decyl Ester A gelatinous dispersion of the sodium salt of ethylenedinitrilotetraacetic acid, N,N-didodecyl ester was made by reacting at room temperature 13.95 grams of ethylenedinitrilotetraacetic acid, N,N'-didodecyl ester (0.022 mole) with 22 ml. of 200 normal aqueous sodium hydroxide in 200 ml. of water and stirring the reaction mixture vigorously for 30 minutes. 4.36 grams of manganese chloride tetrahydrate dissolved in 20 ml of distilled water was added dropwise at room tempera ture over a period of about 20 minutes. The resulting white precipitate was allowed to stir for 2 hours. It was then filtered and washed with cold water until almost free of chloride ion. The filter-cake was then dried in the vacuum dessicator over calcium sulfate for 44 hours at 0.1 to 0.5 mm Hg. pressure, yielidng a white powder weighing 14.4 grams and melting at 265-270C to a clear melt.
Copper Complex of Ethylenedinitrilotetraacetic Acid, N,N'-di-n-dodecyl Ester The copper complex was made following the procedure of Example 7. 0.022 mole of the disodium salt of ethylenedinitrilotetraacetic acid, N,N'-didodecyl ester,
fomied in situ, was reacted wtih 0.022 mole of cupric chloride dihydrate. The product was a light blue powder which. after drying, melted at 220 to 230C with decomposition.
Analysis 7r Cu H 0 Calculated (l) 9.39 2.54 Found 8.57. 8.34
(l) for the monohydrate EXAMPLE 9 Analysis 7r Zn 7! H O Calculated (l) 8.98 4.95 Found 9.38. 9.75 4.75. 4.63
(l) for the dihydrah:
EXAMPLE 10 Light Stabilization Tests A. Outdoor Exposure Tests a. Sample Preparation 5 mil Oriented Monofilaments The nickel complex of di-n-octadecyl ester of ethylenedinitrilo tetraacetic acid was dissolved in distilled methylene chloride and blended with polypropylene (Hercules Profax 6501) in a Hobart mixer. A buffer (such as calcium stearate) and antioxidant (dioctadecyl (3,5-di-t-butyl-4-hydroxybenzyl) phosphonate) were added to the polymer blend. To facilitate moisture removal all blends are vacuum dried shortly before extrusion. Samples were also prepared containing the additional U V stabilizer (2-(3,5-di-t-butyl-2- hydroxyphcnyl )-5 '-chlorobenzotriazole.
Samples were processed as follows:
I. Compounding and Pelletizing 1 inch Extruder -L/D /1 at 40 rpm Melt Temperature 450F 2. Monofilament Melt Temperature 500F 1 Inch Extruder L/D 24/1 at 20 rpm Spinnerette 1 hole, 20 mil diameter/hole Air cooling was accomplished by spinning into a cooling tower 6 feet X 6 inches X 5 inches fitted with a fan delivering 65 cfm. of air.
3. Filament TakeUp The cooled monafilament was wound on Godet rolls at a filament speed of 500 ft/min.
4. Orientation Godet Temperature 257F Orientation Ratio b. Test Method for Weathering Stability The monofilament was exposed 45 south direct in Florida. Tensile measurements were performed at each exposure interval with the lnstron Model TM.
The results indicated below show the number of kilolangleys (kl) to 50 percent retention of tensile strength. A Langley is a measure of energy in the ultraviolet region to which the samples have been exposed.
KL to 50% Retention of Tensile Strength Formulation (a) 5% nickel complex of -Continued KL to Retention of Tensile Strength Formulation of ethylenedinitrilotetraacetic acid 0.2% di-octadecyl (3.5-dit-butyl-4-hydroxylbenzyl) phosphonate 0.l?i calcium stcaratc (c) 0.2% di-octadecyl (3.5-di-tbutyl-4-hydroxybe nzyl) phosphonate 0. l 7: calcium stearate Improved stabilization of polypropylene to U V light is also obtained when the zinc, manganese, nickel, cobalt, chromium, copper, aluminum, titanium, and iron complexes of di-n-octadecyl ester of ethylenedinitrilo tetraacetic acid is substituted in each case for the above mentioned nickel complex.
B. Artificial Light Exposure Test Deterioration of most polymers caused by ultraviolet light is so slow at ambient temperatures, even in the absence of stabilizers, that testing of the effects of stabilizers generally must be conducted either at higher terriperatures or in an accelerated artificial light exposure device in order to yield results in a convenient period of time. The tests conducted on polymers using an artificial light exposure device is described below:
a. Sample Preparation 25 mil Plaques Unstabilized polypropylene powder (Hercules Profax 6501 is thoroughly blended with the indicated amounts of additives. The blended material is then milled on a two roll mill for 5 minutes at 182. The milled sheet is then compression molded at 220C into 25 mil thick plaques under a pressure of psi and water cooled in the press.
b. Testing Method This test is conducted in a FS/BL unit, basically of the American Cyanamid design, which consists of 40 tubes of alternating fluorescent sun lamps and black lights (20 of each). The 25 mil sample plaques which are mounted on white cardboard stock areplaced on a rotating drum 2 inches from the bulbs. The plaques are exposed in the FS/BL unit until they become sufficiently brittle to break cleanly when bent 180. The results are recorded as hours of exposure to embrittlement.
Thc'test results reported below were obtained according to the procedures described above; The amounts of the additives are expressed in weight percent based on the weight of the polymer.
Hours to Formulation Brittleness (a) 0.5% nickel complex of N.N'- di-n-octadecyl ester of ethylenedinitrilotetraacetic -Continued Hours to Formulation Brittleness acid (Ex. I) 0.1% of di-octadccyl (3.5- di-t'butyM-hydroxybcnzyl) phosphonate (di-oetadecyl (3.5-di-t butyl-4hydroxybenzyl) Phosphonatc is an antioxidant which aids in processing the polymer.
When compared to a sample of unstabilized polypropylene tested according to this same procedure the stabilized sample containing the nickel complex was significantly more stable.
improved stabilization of polypropylene is obtained when the nickel complex of dimethyl, dibutyl and di-ndodecyl esters of ethylene dinitrilo tetraacetic acid is used in place of the nickel complex of the dimoctadecyl ester.
EXAMPLE 1 l Nickel complexes of the dimethyl, di-n-dodecyl and di-n-octadecyl esters of ethylenedinitrilotetraacetic acid are separately incorporated into polypropylene at a concentration providing a nickel concentration of 0.12 percent. The samples are then dyed with Poly Orange RM, Poly Dark Blue 28M and Poly Brilliant Yellow GM. All the samples dye well with all the above dyes.
EXAMPLE 12 EXAMPLE 13 EXAMPLE 14 A stabilized polyamide (nylon 6,6) is prepared by separately incorporating therein 1.0 percent by weight of each of the following metal complexes:
a. manganese complex of di-n-dodecyl ester of ethylenedinitrilotetraacetic acid b. manganese complex of di-n-butyl ester of ethyl enedinitrilotetraacetic acid c. copper complex of di-n-dodecyl ester of ethylenedinitrilotetraacetic acid d. nickel complex of di-n-dodecyl ester of ethylenedinitrilotetraacetic acid 1 EXAMPLE 15 I A stabilized polyethyleneterephthalate is prepared by incorporating therein 1.0 percent by weight of the zinc complex of di-n-dodecyl ester of ethylenedinitrilotetraacetic acid.
EXAMPLE 16 A stabilized polycarbonate is prepared by separately incorporating therein 1.0 percent by weight of each of the following metal complexes:
a. nickel complex of di-n-octadecyl ester of ethylenedinitrilotetraacetic acid b. nickel complex of di-n-butyl ester of ethylenedinitrilotetraacetic acid.
What is claimed is:
l. A composition of matter stabilized against ultraviolet deterioration which comprises a synthetic organic polymer normally subject ot ultraviolet deterioration containing from 0.1 percent to 5 percent by weight of the polymer of a metal complex of a dialkyl ester of ethylenedinitrilotetraacetic acid having the formula:
6" o R-Oii-OHr-N-OHz-ii-O- 0 Hz 0 ll ll R-O -CH7-N-CHg- 0 n wherein R is an alkyl group of from one to 18 carbon'atoms;
M is selected from the group consisting of zinc, manganese, nickel, cobalt, chromium, copper, aluminum, titanium and iron and n has a value of from 1 to 3, the value of n being the same as the available valence of M.
2. The composition of claim 1 wherein M is nickel, manganese, copper or zinc.
3. The composition of claim 1 wherein R is noctadecyl, n-butyl or n-dodecyl.
4. The composition of claim I wherein M is nickel and R is n-octadecyl.
5. The composition of claim 1 wherein M is nickel and R is n-butyl.
6. The composition of claim 1 wherein M is nickel and R is n-dodecyl.
7. The composition of claim 1 wherein M is manganese and R is n-butyl.
8. The composition of claim 1 wherein M is manganese and R is n-dodecyl.
9. The composition of claim 1 wherein M is copper and R is n-dodecyl.
10. The composition of claim 1 wherein M is zinc and R is n-dodecyl.
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|U.S. Classification||524/239, 426/268|
|International Classification||C08K5/00, C08K5/17|
|Cooperative Classification||C08K5/0091, C08K5/175|
|European Classification||C08K5/17B, C08K5/00S|