|Publication number||US6227040 B1|
|Application number||US 09/017,765|
|Publication date||May 8, 2001|
|Filing date||Feb 3, 1998|
|Priority date||Feb 3, 1998|
|Also published as||CA2258329A1, CA2258329C, CN1130555C, CN1233752A, EP0933632A2, EP0933632A3, EP0933632B1, US6446494, US20010039830|
|Publication number||017765, 09017765, US 6227040 B1, US 6227040B1, US-B1-6227040, US6227040 B1, US6227040B1|
|Inventors||Calvin R. Hastings, Herbert Estrada, Steven J. Johnson, Robert C. Miller, Donald R. Augenstein|
|Original Assignee||Caldon, Inc.|
|Export Citation||BiBTeX, EndNote, RefMan|
|Patent Citations (14), Referenced by (43), Classifications (12), Legal Events (7)|
|External Links: USPTO, USPTO Assignment, Espacenet|
The present invention is related to the measurement of fluid viscosity in a container, such as a drum, tank or pipe. More specifically, the present invention is related to the determination of the viscosity of a fluid in a container by determining the attenuation of an acoustic signal traveling through the fluid and the speed of sound of the fluid. The fluid may be at rest or in motion.
In petroleum and other pipelines, there exists a need to measure certain properties of the fluid, which generally is flowing.
In particular, a measurement of viscosity (either absolute or kinematic) is needed to:
(a) differentiate fluids,
(b) detect the interface between two different fluids,
(c) characterize pressure gradients in a pipeline for purposes of leak detection and locations,
(d) determine when a change or interface between fluids occur, and
(e) determine the required amount of dilution agent to meet the maximum viscosity limit set by the pumping power and pressure rating of the pipeline.
Currently available means for these measurements are complex, expensive, and sometimes unreliable. For example, viscous forces are sometimes measured by vibratory systems. For these means and most others, a bypass line is necessary to direct a fraction of the flowing fluid to the means of measurement. The bypass can become obstructed with waxes or other elements carried by the flowing fluid. In addition, the moving parts of such measurement means can create maintenance and calibration problems. Many pipeline operators take grab samples of the flowing fluid to determine density and viscosity, because the accuracy and reliability of the on-line means do not meet their requirements. The expense of the sampling procedure is obvious. In addition, the procedure deprives the pipeline operator of the ability to monitor and control the properties continuously and in real time.
The present invention pertains to an apparatus for measuring the viscosity of a fluid in a container, such as a pipe. The apparatus comprises a mechanism for transmitting an acoustic signal through the fluid in a container. The transmitting mechanism provides the signal to the fluid in the container. The apparatus comprises a mechanism for receiving the signal after the signal has passed through the fluid. The receiving mechanism receives the signal from the fluid in the container. The apparatus comprises a mechanism for determining the fluid viscosity in the container from the signal after the signal has passed through the fluid. The determining mechanism is connected to the receiving mechanism.
The present invention pertains to a method for measuring the viscosity of a fluid in a container, such as a pipe. The method comprises the steps of transmitting a signal into fluid. Then there is the step of receiving the signal after it has passed through the fluid. Next there is the step of determining the attenuation of the signal after the signal has passed through the fluid. Then there is the step of finding the viscosity of the fluid in the pipe from the attenuation of the signal and its transit time, the latter being a measure of sound velocity in the fluid.
The mechanism may use transducers affixed to the outside of the container, such as a pipe, (i.e., external transducer) or transducers penetrating the container (i.e., wetted transducer).
In the accompanying drawings, the preferred embodiment of the invention and preferred methods of practicing the invention are illustrated in which:
FIGS. 1a and 1 b are schematic representations of side and axial views, respectively, of transducers placed on a pipe.
FIGS. 2a and 2 b are schematic representations of the acoustic path with external transducers and wetted transducers, respectively.
FIG. 3 is a representation of time delay and signal attenuation of a typical oscillograph regarding the present invention.
FIG. 4 is a schematic representation of the present invention.
FIG. 5 is a schematic representation of an alternative embodiment of the present invention.
FIG. 6 is a graph of ASPREAD verses Cf.
Referring now to the drawings wherein like reference numerals refer to similar or identical parts throughout the several views, and more specifically to Figure thereof, there is shown an apparatus 10 for measuring the viscosity of a fluid in a container 12, such as a pipe. The apparatus 10 comprises a mechanism 14 for transmitting a signal into a fluid 21 in a container 12. The transmitting mechanism 14 is adapted to contact the container 12 and provide the signal to the fluid 21 in the container 12. The apparatus 10 comprises a mechanism 16 for receiving the signal after the signal has passed through the fluid 21. The receiving mechanism 16 contacts the container 12 and receives the signal from the fluid 21 in the container 12. The apparatus 10 comprises a mechanism 15 for determining the viscosity of the fluid in the container 12 from the signal after the signal has passed through the fluid 21. The determining mechanism 15 is connected to the receiving mechanism 16. The determining mechanism 15 is connected to the receiving mechanism 16 and transmitting mechanism 14.
Preferably, the transmitting mechanism 14 and the receiving mechanism 16 are disposed on the external surface 18 of the pipe 12 and the signal passes from the transmitting mechanism 14 through the pipe wall 20, through the fluid 21 in the pipe 12 and through the pipe wall 20 to the receiving mechanism 16. Preferably, the transmitting mechanism 14 and the receiving mechanism 16 contact the wall of pipe 12 or penetrates pipe 12 so the signal from the transmitting mechanism 14 follows a path 22 (either diametric or diagonal) through the pipe 12 to the receiving mechanism 16. The transmitting mechanism 14 and the receiving mechanism 16 are preferably disposed on the pipe 12 opposite each other so the signal from the transmitting mechanism 14 follows a path 22 to the receiving mechanism 16. Preferably, the fluid 21 is a liquid and the transmitting mechanism 14 includes a first transducer 24 which produces an acoustic signal and the receiving mechanism 16 includes a second transducer 26 which receives the acoustic signal from the first transducer 24. The acoustic signal produced by the first transducer 24 preferably passes through the pipe wall 20 into the liquid in the pipe 12 and through the pipe wall 20 to the second transducer 26.
The transmitting mechanism 14 preferably includes a transmitter 28 which applies a first voltage signal to the first transducer 24 causing the first transducer 24 to produce the acoustic signal having frequency f. The transmitter 28 is connected to the first transducer 24. The transmitting mechanism 14 preferably includes a first voltage measuring mechanism 30 connected to the transmitter 28 which measures the voltage applied to the first transducer 24 from the transmitter 28, and records the time at which the voltage was applied.
The receiving mechanism 16 preferably includes a receiver 34 connected to the second transducer 26. The second transducer 26 converts the acoustic signal to a second voltage signal. The receiver 34 amplifies the second voltage signal from the second transducer 26. The receiving mechanism 16 preferably includes a second voltage measuring mechanism 32 connected to the receiver 34 which measures the voltage of the second voltage signal and records the time at which the voltage was received.
The determining mechanism 15 preferably includes a processor mechanism 36 which is connected to the first and second voltage measuring mechanisms 30, 32 and determines the fluid viscosity in the pipe 12 as a function of the voltage and transit time (time between transmit recorded by 30 and receive recorded by 34) measured by the first and second voltage measuring mechanism 30, 32. Preferably, the determining mechanism 15 includes a timing mechanism 32 for measuring transit time of the ultrasonic signal passing through a known distance in the liquid and wherein the processor mechanism 36 determines the liquid sound velocity. Preferably, the processor determines the viscosity as a function of the attenuation of the acoustic signal produced by the first transducer 24 and received by the second transducer 26 as it passes through a known distance in the liquid and the velocity of sound of the liquid which is determined from the transit time. Preferably, the processor determines the viscosity at the time and conditions when the acoustic signal passes through the liquid from the attenuation of the acoustic signal and the velocity of sound of the fluid at the time and the pipe 12. Preferably, the acoustic signal produced by the first transducer 24 and received by the second transducer 26 is an ultrasonic signal.
In an alternative embodiment (FIG. 5), the transmitting mechanism 14 preferably includes a transducer 24 which produces an ultrasonic signal which is sent into the liquid. The transmitting mechanism 14 preferably includes a transmitter 28 which applies a voltage signal to the transducer 24. The transmitting mechanism 14 preferably includes a voltage measuring mechanism 30 which measures the voltage applied and records the transmit time. The transmitting mechanism 14 includes a multiplexer 40 connected to the transmitter 28 and the transducer 24 that switches the first voltage signal to the transducer 24.
Preferably, the multiplexer 40 is used to time share the transducer 24 between the transmitting mechanism 14 and the receiving mechanism 16. When connected to the receiving mechanism 16, the transducer 24 converts received ultrasonic signals it receives from the fluid after the ultrasonic signals have been reflected within the pipe 12 into voltage signals. There is also a receiver 34 which receives and amplifies the voltage signals. The receiver 34 is connected to the multiplexer 40. The multiplexer 40 switches the later voltage signals from the transducer 24 to the receiver 34.
The receiving mechanism 16 preferably includes a second voltage measuring mechanism 32 connected to the receiver 34 which measures the voltage of the later voltage signal and records when the voltage was received. Preferably, the determining mechanism 15 includes a processor mechanism 36 which is connected to the first and second voltage measuring mechanisms 30, 32 and determines the fluid viscosity in the pipe 12 as a function of the voltages measured by the first and second voltage measuring mechanisms 30 and 32 and the transit time between the transmit signal recorded by 30 and the received signal recorded by 32.
In general, an acoustic path (See FIGS. 2a and 2 b) will be comprised of a number of interfaces, attenuating media and reflections as follows:
(1) Transducer 1/acoustic housing 24 interface (FIGS. 2a and 2 b).
(2) Transducer housing 24 attenuation (FIGS. 2a and 2 b).
(3) Transducer Housing 24/container wall 20 interface (for external transducers) (FIG. 2a).
(4) Container wall 20 attenuation (for external transducers) (FIG. 2a).
(5) Container wall 20/fluid interface (for external transducers) (FIG. 2a) and the housing 24 to fluid interface (for wetted transducers) (FIG. 2b).
(6) Fluid attenuation (FIGS. 2a and 2 b)
The attenuation will depend on the fluid viscosity, the acoustic path length, and the ultrasound frequency, among other factors.
(7) Container Wall 20 Reflections (as applicable)
(8) Fluid/container wall 20 interface (for external transducers (FIG. 2a) and the fluid/housing 20 interface (for wetted transducers) (FIG. 2b).
(9) Container wall 20 attenuation (for external transducers) (FIG. 2a).
(10) Container wall 20/transducer housing 26 interface (for external transducers) (FIG. 2a).
(11) Transducer Housing 26 attenuation (FIGS. 2a and 2 b).
(12) Transducer Housing 26/transducer 2 interface (FIGS. 2a and 2 b).
As it makes its way from the electrical transmitter to the electronic receiver, the transmitted energy will be attenuated electrically as well as acoustically. The electrical cable, the electrical/acoustic transduction properties of the transmitting and receiving transducers, and the voltage amplification characteristics of the electronic receiver contribute to the determination of the net magnitude of the signal as measured at the electronic receiver output. There are also potential sources of attenuation due to non-ideal coupling at interfaces (1), (3), (10), and (12).
The apparatus 10 (FIGS. 4 and 5) preferably rely on the physical principles described next.
The acoustic transducer is reciprocal. When excited with voltage pulses, the transducer produces pressure waves, and when subjected to pressure waves produce a voltage. The pressure propagates from the transmitting transducer through each of the media to the receiving transducers. The apparatus 10 makes use of reflected acoustic energy as well as transmitted acoustic energy.
1. Non-Fluid Attenuation AEXT.
The attenuation which result from a number of sources which are not dependent of the fluid contained in the pipe is referred to as AEXT (decibels). Included in these are the efficiency of conversion of electrical energy to ultrasonic energy and ultrasonic energy to electrical energy by the transmitting and receiving transducers, the efficiency of the coupling from the transducer to the pipe wall and pipe wall to transducer, the gain of the receiver, etc. All of these sources of attenuation are typically combined.
2. Transmitted Energy at a Media Interface, ATRANS and AREF.
When acoustic energy encounters an interface between two media of differing densities and ultrasound transmission velocities, the (acoustic energy) of the transmitted wave is attenuated (decibels) according to the following equation:
Likewise, the acoustic energy is attenuated (decibels) as follows:
ρi=density of medium i
Ci=propagation velocity of the ultrasound in medium i
1=subscript for the incident medium
2=subscript for the refracting medium
ATRANS=Attenuation in dB for energy transmitting through a medium interface
AREF=Attenuation in dB for energy reflected at a medium interface
3. Fluid Acoustic Absorption Avis.
As ultrasonic energy travels through a viscous fluid some of the energy is dissipated in losses, the magnitude of which is related to the viscosity, the density, and the propagation velocity and frequency of the ultrasound. These losses are characterized by an attenuation constant given by a relationship of the following form:
a=the attenuation constant in inverse length
w=angular frequency (radians/second)
C=propagation velocity of ultrasound (in/s)
η=absolute shear viscosity (poise)
ηB=absolute bulk viscosity (poise)
ρ=mass density of the fluid (gm/cm3)
a,b=constants relating shear and bulk viscosity, determined by the molecular structure of the fluid. Theoretically, oil products have a=4/3 and b=1.
The attenuation of the acoustic energy in the viscous fluid is related exponentially to the attenuation coefficient and the distance the acoustic energy travels through the fluid. For an acoustic wave traveling across a pipe, the acoustic energy reaching the far wall is given by:
AVIS=attenuation due to viscosity losses (dB)
The viscosity correction factor is in general unknown and ideally is determined for all fluids that might be expected to be encountered. Practically, it may be approximated as two for most fluids that will be encountered excluding water for which it is approximately three.
4. Spreading Attenuation ASPREAD.
When a beam of ultrasonic energy propagates through a media after some distance it spreads out, that is, its width increases as the distance from the source increases. Since the size of the receiving transducer is fixed, then as the distance between the transmitting and receiving transducers increases the amount of energy incident on the receiving transducer decreases. In the limit of large distance, the spreading attenuation is given by the equation
ASPREAD the spreading attenuation in dB
f, cf, and L defined as before
KS=a constant dependent on the dimensions and properties of the transducer
Since KS is fixed, i.e. not dependent on the fluid, it is sometimes contained in AEXT. FIG. 6 shows the calculated dependence of the spreading attenuation on frequency for a system composed of two one inch diameter transducers mounted on pipes of various inside diameters. As can be seen, the behavior for pipes over sixteen inches ID are in reasonable agreement with the above equation for smaller size pipes there is a region where the spreading attenuation is nearly independent of the sound velocity and for smaller distances the attenuation increases as the sound velocity increases.
The apparatus 10 makes use of the dependence of the received voltage signal on the attenuation characteristics of interfaces (5) and (7) of the above list, as well as the fluid attenuation characteristic (6).
The equations describing the physical principles underlying the invention previously given show that the attenuation of the acoustic signal at the container wall/fluid interfaces is a function of the density sound velocity product for the fluid and the pipewall material.
In order to calculate the attenuation, the sound velocity in the fluid is determined using pulse transit time data measured for the acoustic path, in conjunction with delay times for the non-fluid media.
Specifically, the ultrasound velocity is given by:
tf=the mean transit time of acoustic pulses traveling normal to the pipe axis in the fluid
L=acoustic path length in fluid
tTOTAL=the total transit time from electronic transmitter through to electronic receiver.
tnon-fluid=the total of all non fluid delays including transit times for cables, transducers and housings, pipewalls and receiving electronics.
The density of the pipewall material is usually well known or can be determined before making the fluid property measurements. The sound velocity of the pipewall material is often known or, if not, can be measured using the ultrasonic thickness means. To calibrate the property measurement device for density, the density of one of the unknown fluids flowing in the pipe can be measured by means of a grab sample or determined by a sound velocity to density relationship.
The natural frequency of transmitting and receiving transducers is chosen to produce significant attenuation in the fluid itself for the full range of viscosities to be measured.
The viscosity measuring acoustic path can be calibrated by measuring the attenuation with a fluid whose viscosity is determined accurately by means of a grab sample. The viscosity of another fluid can then be determined from the attenuation measured for that fluid relative to the attenuation measured for the calibration fluid.
In one embodiment, the attenuation measurement necessary for the viscosity determination is effected by means of an automatic gain control feature applied to the receiver amplifier that processes the received acoustic pulse for amplitude and transit time determination. The automatic gain control senses the amplitude of the received signal after amplification and compares it with a preset reference. If the signal is below the reference, the gain is increased, if above the reference, the gain is decreased. The magnitude of the gain necessary to achieve this equilibrium is a direct measure of the attenuation to be measured. When the gain required for an unknown fluid is compared with the gain required with a reference fluid, the viscosity can be calculated using the relationships heretofore described.
Consider the case of two ultrasonic transducers placed at diametrically opposed positions on a length of pipe containing a fluid. As shown in FIG. 4, transmitter 28 applies a known voltage pulse to a first ultrasonic transducer 24. A first voltage measuring mechanism 30 (for example, a simple voltmeter) which measures the voltage applied to the first transducer 24. When the voltage pulse is applied to the first transducer 24, it generates an ultrasonic signal of frequency f which propagates through the pipe wall 20, fluid 21, and opposed pipe wall 20 to second transducer 26. At the second transducer 26, the ultrasonic signal is converted into an electrical signal which is amplified by the receiver 34 and connected to a second voltage measuring mechanism 32. The attenuation expressed in dB is calculated by the equation
where V1 is the voltage measured by second voltage measuring mechanism 32 and V2 by first voltage measuring mechanism 30. The measured attenuation AMES results from the sum total of all types of attenuation, namely AEXT, ATRANS, AVIS, AREF, and ASPREAD. For an arrangement as shown in FIG. 4, the AMES is equal to:
Another possible arrangement is to use a single transducer as shown in FIG. 5. Here, the signal voltage is measured after two passages (out and back) through the fluid and after being reflected three times by the pipe wall making four passes (out and back twice) through the fluid. In this case, the total attenuation for two passages is given by:
when the pulse is detected after four passes through the fluid, the total attenuation is given by:
Subtracting Eqs. G from H
The advantage of this approach is that it is not necessary to determine ATRANS and AEXT. Additionally, the system requires fewer transducers.
Three different samples of crude oil were measured in a pipeline having an inside diameter of 23.23 inches. The density of the steel from which the pipe was formed was 7.71 grams/cubic cm and its sound velocity for a compressional wave 232,437 inches/sec.
The sound velocity of these fluids were measured as described in U.S. Pat. No. 5,546,813, incorporated by reference herein, and the attenuation was measured as described above and calculated using Eq. E
The following results were obtained:
cf = 50101 inches/sec
AMES = −29.0 dB
cf = 52307 inches/sec
AMES = −36.4 dB
cf = 55452 inches/sec
AMES = −46.4 dB
For this class of materials it has been determined (a number of different samples of products mentioned above were obtained and the density and velocity of sound measured. The results were plotted and fitted to a linear equation using the method of least squares) that the density in grams/cubic cm can be related to the measured velocity of sound in inches/sec by the equation
In order to determine the viscosity of these fluids, it is necessary to know the value of AEXT. Since it is difficult to determine this quantity directly, it will be estimated by using the known viscosity of one of the products. 18G was chosen for this purpose since it has the lowest total attenuation and, thus, least susceptible to errors in the measured viscosity. Further since the pipe diameter is large, Eq. D is applicable. For 18G, the measured viscosity at the temperature of the fluid in the pipe at the time the attenuation measurement was 3.43 centipoises Using the measured sound velocity, assuming Kv=2.0 and the equations A, D, and C, one can calculate
and since AMES=−29 dB it is found from Eq F that AEXT=−6.32 dB
Calculating ATRANS and ASPREAD using Eqs A & D for WCH, it is found
and then from Eq. F
and the calculated viscosity from Eq C is 63.1 centipoises.
Calculating ATRANS and ASPREAD for OCS using Eqs. A & D, it is found
and then from Eq. F
and the calculated viscosity assuming Kv=2.0 is from Eq. C 179.0 centipoises. This can be compared with a measured value of a sample of OCS at 180 centipoises
The difference in attenuation for four passes and two passes (AMES4−AMES2) in a short length rectangular pipe (of 9.5 inch by 5.5 inch inside dimensions) with the sound propagating parallel to the long dimension, were measured for three liquids having different velocities of sound and all having low fluid attenuation at the measuring frequency (1.0 MHZ) as a result of low viscosity, giving the (AMES4−AMES2) results
Water −8.2 dB
Ethyl alcohol −4.2 dB
Kerosene −5.4 dB
The properties of these materials and the calculation of the spreading attenuation is summarized using Eqs. D, B, and K in the table
AVIS4 − AVIS2 dB
2 · AREF dB
ASPREAD4 − ASPREAD2 dB
Using the method of least squares, the difference in spreading attenuation was fitted to the equation
For a sample of mineral oil of unknown viscosity the measured value of AMES4−AMES2 in the same section of pipe was −21.3 dB. and the measured value of the velocity of sound was 57304 inches/sec. The measured value of the density in a separate experiment was 0.93 grams/cc.
The following quantities were calculated using Eqs. B, and E2, and K
then from Eq. K
and from Eq. B and using Kv of 2.84
This can be compared to the measured value of 125-130 cS.
The difference in attenuation for four passes and two passes (AMES4−AMES2) in a short length rectangular pipe (of 9.5 inch by 5.5 inch inside dimensions) with the sound propagating parallel to the short dimension, were measured for two liquids having different velocities of sound and having low viscosity and as a result low fluid attenuation at the measuring frequency (5.0 MHZ) giving the (AMES4−AMES2) results
Water −6.3 dB
Ethyl alcohol −12.3 dB
The properties of these materials and the calculation of the spreading attenuation is summarized using Eqs D, B, and K in the table
2.8 previously tested
AVIS4 − AVIS2 dB
2 · AREF dB
ASPREAD4 − ASPREAD2
5.0 × 106
5.0 × 106
Using a straight line fit, a spreading attenuation was fitted to the equation
For a sample of kerosene oil, the measured value of AMES4−AMES2 in the same container was 12.3 dB. and the measured value of the velocity of sound was 50848 inches/sec. The measured value of the density in a separate experiment was 0.843 grams/cc.
The following quantities were calculated using Eqs. B, and E3 and K
then from Eq. K
and from Eq. B
This can be compared to the predicted value of 2.5 centipoise.
Although the invention has been described in detail in the foregoing embodiments for the purpose of illustration, it is to be understood that such detail is solely for that purpose and that variations can be made therein by those skilled in the art without departing from the spirit and scope of the invention except as it may be described by the following claims.
|Cited Patent||Filing date||Publication date||Applicant||Title|
|US2768524 *||Oct 6, 1953||Oct 30, 1956||Honeywell Regulator Co||Ultrasonic absorption measuring apparatus|
|US3392574 *||Jun 13, 1966||Jul 16, 1968||Chesapeake Instr Corp||Sing-around velocimeter|
|US3553636 *||Jan 27, 1969||Jan 5, 1971||Bindicator Co||Noncontact ultrasonic interface viscosity and percent solid detecting device|
|US3720105 *||Mar 24, 1971||Mar 13, 1973||Nusonics||Acoustic flowmeter|
|US4065958 *||Oct 18, 1976||Jan 3, 1978||Eleonora Dmitrievna Krylova||Method of controlling physical characteristics of fluid medium|
|US4095457 *||Jun 21, 1977||Jun 20, 1978||Nippon Kokan Kabushiki Kaisha||Apparatus for detecting changes in parameters of liquid flowing in a pipe based on sing-around method|
|US4331025 *||Oct 14, 1980||May 25, 1982||Mapco, Inc.||Methods of measuring fluid viscosity and flow rate|
|US4559810 *||Jun 15, 1984||Dec 24, 1985||Applied Polymer Technology, Inc.||Method for determining resin viscosity with ultrasonic waves|
|US5271267 *||Mar 9, 1992||Dec 21, 1993||Joseph Baumoel||Method and apparatus for determining fluid properties from sonic/temperature fluid signature|
|US5359897 *||Aug 8, 1990||Nov 1, 1994||Front Engineering Ltd.||Apparatus for determining the time taken for sound energy to cross a body of fluid in a pipe|
|US5365778 *||Jan 28, 1994||Nov 22, 1994||The University Of Chicago||Method for measuring liquid viscosity and ultrasonic viscometer|
|US5433112 *||Sep 29, 1992||Jul 18, 1995||Piche; Luc||Ultrasonic characterization of polymer melts under processing conditions|
|US5557047 *||Feb 1, 1994||Sep 17, 1996||Fuji Ultrasonic Engineering Co., Ltd.||Method and apparatus for ultrasonic wave measurement|
|US5686661 *||Jun 4, 1996||Nov 11, 1997||Mississippi State University||In-situ, real time viscosity measurement of molten materials with laser induced ultrasonics|
|Citing Patent||Filing date||Publication date||Applicant||Title|
|US6763698||Mar 15, 2002||Jul 20, 2004||Battelle Memorial Institute||Self calibrating system and technique for ultrasonic determination of fluid properties|
|US6912891||Jun 21, 2002||Jul 5, 2005||The Penn State Research Foundation||Characterization of fluids using ultrasound|
|US6938995||Dec 4, 2002||Sep 6, 2005||Picoliter Inc.||Acoustic assessment of fluids in a plurality of reservoirs|
|US7152490||Aug 15, 2005||Dec 26, 2006||Daniel Measurement And Control, Inc.||Methods for determining transducer delay time and transducer separation in ultrasonic flow meters|
|US7204129 *||Feb 7, 2006||Apr 17, 2007||L M International Corporation||Real-time system for detecting foreign bodies in food containers using ultrasound|
|US7213445||Sep 23, 2004||May 8, 2007||Wayne State University||Acoustic particulates density sensor|
|US7354141||Jan 31, 2005||Apr 8, 2008||Labcyte Inc.||Acoustic assessment of characteristics of a fluid relevant to acoustic ejection|
|US7395711||Jan 19, 2005||Jul 8, 2008||Battelle Memorial Institute||System and technique for characterizing fluids using ultrasonic diffraction grating spectroscopy|
|US7454958||Sep 20, 2004||Nov 25, 2008||Labcyte Inc.||Acoustic determination of properties of reservoirs and of fluids contained therein|
|US7618820 *||Jun 30, 2004||Nov 17, 2009||Depuy Products, Inc.||System and method for determining the operating state of orthopaedic admixtures|
|US7717544||Oct 1, 2004||May 18, 2010||Labcyte Inc.||Method for acoustically ejecting a droplet of fluid from a reservoir by an acoustic fluid ejection apparatus|
|US7748256||Jul 3, 2007||Jul 6, 2010||Caterpillar Inc.||Nondestructive testing of torsional vibration dampers|
|US7784331 *||Aug 6, 2008||Aug 31, 2010||Labcyte Inc.||Acoustic determination of properties of reservoirs and of fluids contained therein|
|US7899645||Mar 24, 2008||Mar 1, 2011||Labcyte Inc.||Acoustic assessment of characteristics of a fluid relevant to acoustic ejection|
|US7900505||Jan 10, 2006||Mar 8, 2011||Labcyte Inc.||Acoustic assessment of fluids in a plurality of reservoirs|
|US7915046 *||Nov 10, 2009||Mar 29, 2011||Depuy Products, Inc.||System and method for determining the operating state of orthopaedic admixtures|
|US8394105||Mar 14, 2006||Mar 12, 2013||DePuy Synthes Products, LLC||Apparatus for dispensing bone cement|
|US8574237||Dec 30, 2005||Nov 5, 2013||DePuy Synthes Products, LLC||Method and apparatus for predicting the operating points of bone cement|
|US8845646||Feb 22, 2013||Sep 30, 2014||DePuy Synthes Products, LLC||Apparatus and method for dispensing bone cement|
|US9221250||May 20, 2014||Dec 29, 2015||Labcyte Inc.||Acoustically ejecting a droplet of fluid from a reservoir by an acoustic fluid ejection apparatus|
|US20030150257 *||Dec 4, 2002||Aug 14, 2003||Mutz Mitchell W.||Acoustic assessment of fluids in a plurality of reservoirs|
|US20040119793 *||Nov 6, 2003||Jun 24, 2004||Mutz Mitchell W.||Acoustic assessment of fluids in a plurality of reservoirs|
|US20050076704 *||Sep 23, 2004||Apr 14, 2005||Wu Sean F.||Acoustic particulates density sensor|
|US20050092058 *||Sep 20, 2004||May 5, 2005||Ellson Richard N.||Acoustic determination of properties of reservoirs and of fluids contained therein|
|US20050212869 *||Jan 31, 2005||Sep 29, 2005||Ellson Richard N||Acoustic assessment of characteristics of a fluid relevant to acoustic ejection|
|US20050215902 *||Jan 19, 2005||Sep 29, 2005||Greenwood Margaret S||System and technique for characterizing fluids using ultrasonic diffraction grating spectroscopy|
|US20060000284 *||Jun 30, 2004||Jan 5, 2006||Sherman Jason T||System and method for determining the operating state of orthopaedic admixtures|
|US20060071983 *||Oct 1, 2004||Apr 6, 2006||Stearns Richard G||Method for acoustically ejecting a droplet of fluid from a reservoir by an acoustic fluid ejection apparatus|
|US20060123911 *||Feb 7, 2006||Jun 15, 2006||Basir Otman A||Real-time system for detecting foreign bodies in food containers using ultrasound|
|US20060156797 *||Jan 10, 2006||Jul 20, 2006||Labcyte Inc.||Acoustic assessment of fluids in a plurality of reservoirs|
|US20070154874 *||Dec 30, 2005||Jul 5, 2007||Sherman Jason T||Method and apparatus for predicting the operating points of bone cement|
|US20070233147 *||Mar 14, 2006||Oct 4, 2007||Vendrely Timothy G||Apparatus for dispensing bone cement|
|US20090007629 *||Jul 3, 2007||Jan 8, 2009||Caterpillar Inc.||Nondestructive testing of torsional vibration dampers|
|US20090007676 *||Aug 6, 2008||Jan 8, 2009||Labcyte Inc.||Acoustic determination of properties of reservoirs and of fluids contained therein|
|US20090245976 *||Mar 25, 2008||Oct 1, 2009||Hennig Emmett D||Bale mover|
|US20100050773 *||Nov 10, 2009||Mar 4, 2010||Depuy Products, Inc.||System and Method for Determining the Operating State of Orthopaedic Admixtures|
|US20110166797 *||Jul 12, 2010||Jul 7, 2011||Labcyte Inc.||Acoustic determination of properties of reservoirs and of fluids contained therein|
|US20130031956 *||Apr 15, 2010||Feb 7, 2013||Vasile Mecea||Method for Detecting Gas and a Gas Detector Therefor|
|US20150052981 *||Dec 19, 2013||Feb 26, 2015||Soongsil University Research Consortium Techno-Park||Apparatus and method for measuring the viscosity of a fluid using ultrasonic waves|
|US20150053577 *||Aug 25, 2013||Feb 26, 2015||Alan Joseph Bauer||Devices and methods for identifying a biological or chemical residue in an aqueous sample|
|US20150219541 *||Feb 3, 2014||Aug 6, 2015||Cameron International Corporation||Method and Apparatus for Determining Kinematic Viscosity Through the Transmission and Reception of Ultrasonic Energy|
|DE102006053032A1 *||Nov 10, 2006||May 15, 2008||Schaeffler Kg||Determining the damping properties of greases comprises introducing a layer of grease between two plates, applying an excitation signal to one plate and detecting a response signal from the other plate|
|WO2015116358A1 *||Jan 7, 2015||Aug 6, 2015||Cameron International Corporation||Method and apparatus for determining kinematic viscosity through the transmission and reception of ultrasonic energy|
|U.S. Classification||73/54.41, 73/592|
|International Classification||G01N11/00, G01N29/032, G01N29/02|
|Cooperative Classification||G01N2291/048, G01N2291/02818, G01N2291/102, G01N29/032, G01N2291/015, G01N2291/011|
|Feb 3, 1998||AS||Assignment|
Owner name: CALDON, INC., PENNSYLVANIA
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HASTINGS, CALVIN R.;ESTRADA, HERBERT;JOHNSON, STEVEN J.;AND OTHERS;REEL/FRAME:009009/0414;SIGNING DATES FROM 19971105 TO 19971113
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