Dorai, Kavita and Kumar, Anil (2000) Cross Correlations in the Longitudinal Relaxation of Strongly Coupled Spins. In: Journal of Magnetic Resonance, 145 (1). pp. 8-17.
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A generalized set of magnetization modes for quantifying crosscorrelation contributions to longitudinal relaxation in strongly coupled spin systems is described in this paper. Such a set of modes (called longitudinal multiple-quantum modes) is used to unravel cross-correlation information in strongly coupled systems, where the strength of the J coupling tends to obscure such effects.The applicability of such methods is demonstrated for a small molecule which exhibits some strong coupling effects even at high magnetic field strengths. The contribution of remote cross correlations to the longitudinal relaxation of strongly coupled spins is detailed.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Academic Press.|
|Keywords:||strong coupling;Cross correlations;Single-transition operators;Longitudinal multiple-quantum modes;Remote cross correlations|
|Department/Centre:||Division of Chemical Sciences > Sophisticated Instruments Facility
Division of Physical & Mathematical Sciences > Physics
|Date Deposited:||25 Aug 2008|
|Last Modified:||19 Sep 2010 04:30|
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