Mukhopadhyay, Pritam and Bharadwaj, Parimal K and Krishnan, Anu and Das, Puspendu K (2002) Synthesis and characterization of mono- and bis-D-pi-A cryptand derivatives for second-order nonlinear optics and its modulation with different metal ion inputs. In: Journal of Materials Chemistry, 12 (9). pp. 2786-2791.
Synthesis_and_characterization.pdf - Published Version
Restricted to Registered users only
Download (385Kb) | Request a copy
Two new classes of mono- and bis-D-pi-A cryptand derivatives with a flexible and a rigid cryptand core have been synthesized. The linear and nonlinear optical properties of these molecules are probed. The three dimensional cavity of the cryptand moiety has been utilized to modulate the SHG intensity to different extents in solution with metal ion inputs such as Ni-II,Cu-II,Zn-II, and Cd-II. We also report that decomplexation events can be used to reversibly modulate their NLO responses.
|Item Type:||Journal Article|
|Additional Information:||Copyright of this article belongs to Royal Society of Chemistry.|
|Department/Centre:||Division of Chemical Sciences > Inorganic & Physical Chemistry|
|Date Deposited:||27 Jul 2011 10:20|
|Last Modified:||27 Jul 2011 10:20|
Actions (login required)