Encapsulated Tl(III) strongly retained within an iminophenolate cryptand host
UNSPECIFIED. (2000) Encapsulated Tl(III) strongly retained within an iminophenolate cryptand host. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 8 . pp. 1275-1278. ISSN 0300-9246Full text not available from this repository.
The crystal structure of a thallium(III) iminophenolate cryptate is reported. Tl(III) is strongly held within the host, as judged by NMR indicators of strength of binding, by both imino-N, (via Tl-203,Tl-205,N-15 coupling of over 1000 Hz in the MAS-CP spectrum) and phenolate-O donors (via the weakness of competitive H-bonding to the phenolate O- groups, seen in the solution H-1 spectrum).
|Item Type:||Journal Article|
|Subjects:||Q Science > QD Chemistry|
|Journal or Publication Title:||JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS|
|Publisher:||ROYAL SOC CHEMISTRY|
|Number of Pages:||4|
|Page Range:||pp. 1275-1278|
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