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You have probably also been hearing about the "solar revolution" for the last 20 years -- the idea that one day we will all use free electricity from the sun. This is a seductive promise: On a bright, sunny day, the sun shines approximately 1,000 watts of energy per square meter of the planet's surface, and if we could collect all of that energy we could easily power our homes and offices for free.
In this article, we will examine solar cells to learn how they convert the sun's energy directly into electricity. In the process, you will learn why we are getting closer to using the sun's energy on a daily basis, and why we still have more research to do before the process becomes cost effective.
Converting Photons to
Photovoltaic (PV) cells are made of special materials called semiconductors such as silicon, which is currently the most commonly used. Basically, when light strikes the cell, a certain portion of it is absorbed within the semiconductor material. This means that the energy of the absorbed light is transferred to the semiconductor. The energy knocks electrons loose, allowing them to flow freely. PV cells also all have one or more electric fields that act to force electrons freed by light absorption to flow in a certain direction. This flow of electrons is a current, and by placing metal contacts on the top and bottom of the PV cell, we can draw that current off to use externally. For example, the current can power a calculator. This current, together with the cell's voltage (which is a result of its built-in electric field or fields), defines the power (or wattage) that the solar cell can produce.
That's the basic process, but there's really much more to it. Let's take a deeper look into one example of a PV cell: the single crystal silicon cell.
We've now described pure, crystalline silicon. Pure silicon is a poor conductor of electricity because none of its electrons are free to move about, as electrons are in good conductors such as copper. Instead, the electrons are all locked in the crystalline structure. The silicon in a solar cell is modified slightly so that it will work as a solar cell.
Silicon in Solar Cells
When energy is added to pure silicon, for example in the form of heat, it can cause a few electrons to break free of their bonds and leave their atoms. A hole is left behind in each case. These electrons then wander randomly around the crystalline lattice looking for another hole to fall into. These electrons are called free carriers, and can carry electrical current. There are so few of them in pure silicon, however, that they aren't very useful. Our impure silicon with phosphorous atoms mixed in is a different story. It turns out that it takes a lot less energy to knock loose one of our "extra" phosphorous electrons because they aren't tied up in a bond -- their neighbors aren't holding them back. As a result, most of these electrons do break free, and we have a lot more free carriers than we would have in pure silicon. The process of adding impurities on purpose is called doping, and when doped with phosphorous, the resulting silicon is called N-type ("n" for negative) because of the prevalence of free electrons. N-type doped silicon is a much better conductor than pure silicon is.
Actually, only part of our solar cell is N-type. The other part is doped with boron, which has only three electrons in its outer shell instead of four, to become P-type silicon. Instead of having free electrons, P-type silicon ("p" for positive) has free holes. Holes really are just the absence of electrons, so they carry the opposite (positive) charge. They move around just like electrons do.
So where has all this gotten us?
N-type Plus P-type
Before now, our silicon was all electrically neutral. Our extra electrons were balanced out by the extra protons in the phosphorous. Our missing electrons (holes) were balanced out by the missing protons in the boron. When the holes and electrons mix at the junction between N-type and P-type silicon, however, that neutrality is disrupted. Do all the free electrons fill all the free holes? No. If they did, then the whole arrangement wouldn't be very useful. Right at the junction, however, they do mix and form a barrier, making it harder and harder for electrons on the N side to cross to the P side. Eventually, equilibrium is reached, and we have an electric field separating the two sides.
This electric field acts as a diode, allowing (and even pushing) electrons to flow from the P side to the N side, but not the other way around. It's like a hill -- electrons can easily go down the hill (to the N side), but can't climb it (to the P side).
So we've got an electric field acting as a diode in which electrons can only move in one direction. Let's see what happens when light hits the cell.
When Light Hits the Cell
Each photon with enough energy will normally free exactly one electron, and result in a free hole as well. If this happens close enough to the electric field, or if free electron and free hole happen to wander into its range of influence, the field will send the electron to the N side and the hole to the P side. This causes further disruption of electrical neutrality, and if we provide an external current path, electrons will flow through the path to their original side (the P side) to unite with holes that the electric field sent there, doing work for us along the way. The electron flow provides the current, and the cell's electric field causes a voltage. With both current and voltage, we have power, which is the product of the two.
How much sunlight energy does our PV cell absorb? Unfortunately, the most that our simple cell could absorb is around 25 percent, and more likely is 15 percent or less. Why so little?
Light can be separated into different wavelengths, and we can see them in the form of a rainbow. Since the light that hits our cell has photons of a wide range of energies, it turns out that some of them won't have enough energy to form an electron-hole pair. They'll simply pass through the cell as if it were transparent. Still other photons have too much energy. Only a certain amount of energy, measured in electron volts (eV) and defined by our cell material (about 1.1 eV for crystalline silicon), is required to knock an electron loose. We call this the band gap energy of a material. If a photon has more energy than the required amount, then the extra energy is lost (unless a photon has twice the required energy, and can create more than one electron-hole pair, but this effect is not significant). These two effects alone account for the loss of around 70 percent of the radiation energy incident on our cell.
Why can't we choose a material with a really low band gap, so we can use more of the photons? Unfortunately, our band gap also determines the strength (voltage) of our electric field, and if it's too low, then what we make up in extra current (by absorbing more photons), we lose by having a small voltage. Remember that power is voltage times current. The optimal band gap, balancing these two effects, is around 1.4 eV for a cell made from a single material.
We have other losses as well. Our electrons have to flow from one side of the cell to the other through an external circuit. We can cover the bottom with a metal, allowing for good conduction, but if we completely cover the top, then photons can't get through the opaque conductor and we lose all of our current (in some cells, transparent conductors are used on the top surface, but not in all). If we put our contacts only at the sides of our cell, then the electrons have to travel an extremely long distance (for an electron) to reach the contacts. Remember, silicon is a semiconductor -- it's not nearly as good as a metal for transporting current. Its internal resistance (called series resistance) is fairly high, and high resistance means high losses. To minimize these losses, our cell is covered by a metallic contact grid that shortens the distance that electrons have to travel while covering only a small part of the cell surface. Even so, some photons are blocked by the grid, which can't be too small or else its own resistance will be too high.
Finishing the Cell
The final step is the glass cover plate that protects the cell from the elements. PV modules are made by connecting several cells (usually 36) in series and parallel to achieve useful levels of voltage and current, and putting them in a sturdy frame complete with a glass cover and positive and negative terminals on the back.
Single crystal silicon isn't the only material used in PV cells. Polycrystalline silicon is also used in an attempt to cut manufacturing costs, although resulting cells aren't as efficient as single crystal silicon. Amorphous silicon, which has no crystalline structure, is also used, again in an attempt to reduce production costs. Other materials used include gallium arsenide, copper indium diselenide and cadmium telluride. Since different materials have different band gaps, they seem to be "tuned" to different wavelengths, or photons of different energies. One way efficiency has been improved is to use two or more layers of different materials with different band gaps. The higher band gap material is on the surface, absorbing high-energy photons while allowing lower-energy photons to be absorbed by the lower band gap material beneath. This technique can result in much higher efficiencies. Such cells, called multi-junction cells, can have more than one electric field.
Powering a House
First of all, not every roof has the correct orientation or angle of inclination to take advantage of the sun's energy. Non-tracking PV systems in the Northern Hemisphere should point toward true south (this is the orientation). They should be inclined at an angle equal to the area's latitude to absorb the maximum amount of energy year-round. A different orientation and/or inclination could be used if you want to maximize energy production for the morning or afternoon, and/or the summer or winter. Of course, the modules should never be shaded by nearby trees or buildings, no matter the time of day or the time of year. In a PV module, even if just one of its 36 cells is shaded, power production will be reduced by more than half.
If you have a house with an un-shaded, south-facing roof, you need to decide what size system you need. This is complicated by the facts that your electricity production depends on the weather, which is never completely predictable, and that your electricity demand will also vary. These hurdles are fairly easy to clear. Meteorological data gives average monthly sunlight levels for different geographical areas. This takes into account rainfall and cloudy days, as well as altitude, humidity, and other more subtle factors. You should design for the worst month, so that you'll have enough electricity all year. With that data, and knowing your average household demand (your utility bill conveniently lets you know how much energy you use every month), there are simple methods you can use to determine just how many PV modules you'll need. You'll also need to decide on a system voltage, which you can control by deciding how many modules to wire in series.
If you decide to use batteries, keep in mind that they will have to be maintained, and then replaced after a certain number of years. The PV modules should last 20 years or more, but batteries just don't have that kind of useful life. Batteries in PV systems can also be very dangerous because of the energy they store and the acidic electrolytes they contain, so you'll need a well-ventilated, non-metallic enclosure for them.
The most commonly used deep-cycle batteries are lead-acid batteries (both sealed and vented) and nickel-cadmium batteries. Nickel-cadmium batteries are more expensive, but last longer and can be discharged more completely without harm. Even deep-cycle lead-acid batteries can't be discharged 100 percent without seriously shortening battery life, and generally, PV systems are designed to discharge lead-acid batteries no more than 40 percent or 50 percent.
Also, the use of batteries requires the installation of another component called a charge controller. Batteries last a lot longer if care is taken so that they aren't overcharged or drained too much. That's what a charge controller does. Once the batteries are fully charged, the charge controller doesn't let current from the PV modules continue to flow into them. Similarly, once the batteries have been drained to a certain predetermined level, controlled by measuring battery voltage, many charge controllers will not allow more current to be drained from the batteries until they have been recharged. The use of a charge controller is essential for long battery life.
DC to AC
Throw in the mounting hardware, wiring, junction boxes, grounding equipment, overcurrent protection, DC and AC disconnects and other accessories and you have yourself a system. Electrical codes must be followed (there's a section in the National Electrical Code just for PV), and it's highly recommended that the installation be done by a licensed electrician who has experience with PV systems. Once installed, a PV system requires very little maintenance (especially if no batteries are used), and will provide electricity cleanly and quietly for 20 years or more.
If photovoltaics are such a wonderful source of free energy, then why doesn't the whole world run on solar power? Some people have a flawed concept of solar energy. While it's true that sunlight is free, the electricity generated by PV systems is not. As you can see from our discussion of a household PV system, quite a bit of hardware is needed. Currently, an installed PV system will cost somewhere around $9 per peak Watt. To give you an idea of how much a house system would cost, let's consider the Solar House -- a model residential home in Raleigh, North Carolina, with a PV system set up by the North Carolina Solar Center to demonstrate the technology. It's a fairly small home, and it is estimated that its 3.6-kW PV system covers about half of the total electricity needs (this system doesn't use batteries -- it's connected to the grid). Even so, at $9 per Watt, this installed system would cost you around $32,000.
That's why PV is usually used in remote areas, far from a conventional source of electricity. Right now, it simply can't compete with the utilities. Costs are coming down as research is being done, however. Researchers are confident that PV will one day be cost effective in urban areas as well as remote ones. Part of the problem is that manufacturing needs to be done on a large scale to reduce costs as much as possible. That kind of demand for PV, however, won't exist until prices fall to competitive levels. It's a Catch-22 situation. Even so, demand and module efficiencies are constantly rising, prices are falling, and the world is becoming increasingly aware of environmental concerns associated with conventional power sources, making photovoltaics a technology with a bright future.
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