US 5763735 A
A method of removing radioactivity from the interior of a building by transporting radioactive material within a slurry comprising water and metal salt hydrate, precipitating out or otherwise filtering out the then contaminated material outside the building, thus removing it in a continuous fluid recirculation system, and storing the precipitated out material while providing shielding of radiation, thereby to provide radiation protection without requiring conventional large mass to block the radioactivity. A toxic waste storage facility includes a building having a portion located below ground level, walls for bounding an interior space in the building, and recirculating fluid for removing thermal energy from the building and for providing radioactive shielding and absorption at least at part of the roof of the building.
1. A radioactive material storage facility, comprising:
a building having a portion located below ground level,
wall means for bounding an interior space in the building, and
fluid means for removing thermal energy from the building and for providing radioactive shielding at least at part of a roof of the building, wherein said fluid means comprises a liquid comprising water and a metal salt hydrate.
2. The facility of claim 1, wherein said metal is at least one selected from the group consisting of alkali, alkaline earth and transition metals.
3. The facility of claim 1, wherein said metal is at least one selected from the group consisting of cobalt, magnesium, and sodium.
4. The facility of claim 1, wherein said salt is a sulfate, borate or metaborate salt.
5. The facility of claim 1, wherein said liquid further comprises fines.
6. The facility of claim 1, wherein said liquid further comprises at least one of lead fines or iron fines.
7. The facility of claim 1 further comprising circulating means for circulating at least a portion of said liquid.
8. The facility of claim 1, wherein said wall means comprises light weight panels, said panels comprising at least one of a metal salt hydrate, a plastic or a hydrogen-containing material.
9. The facility of claim 8, wherein said panels comprise Staytex® materials.
10. The facility of claim 8, wherein said facility is earthquake proof.
11. The facility of claim 1, wherein said salt comprises epsom salt, said fluid means comprises a slurry of said epsom salt and water.
12. A radioactive material storage facility comprising:
a building having at least one wall and a roof; and
a fluid system comprising a composition containment means for retrievably holding a composition and a composition comprising water and a metal salt hydrate.
13. The facility of claim 12, wherein said metal is at least one selected from the group consisting of cobalt, magnesium, and sodium.
14. The facility of claim 12, wherein said salt is a sulfate, borate or metaborate salt.
15. The facility of claim 12, wherein said composition further comprises at least one of lead fines or iron fines.
16. The facility of claim 12, further comprising circulating means for circulating at least a portion of said composition.
17. The facility of claim 12, wherein said wall comprises light-weight panels, said panels comprising at least one of a metal salt hydrate, a plastic or a hydrogen-containing material.
18. The facility of claim 17, wherein said panels comprise Staytex® materials.
19. The facility of claim 12, wherein said metal salt hydrate comprises epsom salt, said composition comprises a slurry of said epsom salt and water.
20. A method of effecting radiation shielding and thermal energy removal from a toxic waste storage facility, comprising using a composition comprising water and a metal salt hydrate.
21. The method of claim 20, wherein said metal is at least one selected from the group consisting of alkali, alkaline earth and transition metals.
22. The method of claim 20, wherein said metal is at least one selected from the group consisting of cobalt, magnesium, and sodium.
23. The method of claim 20, wherein said salt is a sulfate, borate or metaborate salt.
24. The method of claim 20, wherein the composition further comprises fines.
25. The method of claim 20, wherein said composition further comprises at least one of lead fines or iron fines.
26. The method of claim 20, wherein said facility comprises at least one wall and a roof, and the method further comprises circulating the composition through at least one wall or roof of the facility.
27. The method of claim 20, further comprising absorbing nuclear radiation in the metal salt hydrate and removing the metal salt hydrate from the composition to reduce the radiation level.
28. The method of claim 27, further comprising reloading the composition with additional metal salt hydrate and recirculating the composition.
29. The method of claim 20, further comprising monitoring the radiation level in the facility and loading an amount of metal salt hydrate in the composition that is proportional to the radiation level.
30. The method of claim 20, wherein said metal salt hydrate comprises epsom salt, said composition comprises a slurry of said epsom salt and water.
31. The method of claim 20, wherein the composition is used as a coolant.
32. A toxic waste depot method comprising using the shielding effect of the ground to tend to prevent leakage of radiation in combination with a fluid of specific gravity characteristic greater than that of water, wherein the fluid comprises water and a metal salt hydrate, to provide both radioactive shielding thermal energy removal functions.
33. A method of generating power comprising generating electric energy from heat removed from the facility of claim 1 with toxic waste stored therein.
34. A method of monitoring of one or more conditions of the toxic waste storage facility of claim 1 in which radioactive material and/or other material therein is stored using detectors and other instrumentation mold molded into prefabricated walls of the facility.
35. The method of claim 34, wherein monitoring of the storage facility is conducted off-site.
This is a continuation-in-part of U.S. patent application Ser. No. 08/184,859, filed Jan. 21, 1994 U.S. Pat. No. 5,498,825, the entire disclosure of which hereby is incorporated by reference.
The present invention relates generally, as is indicated, to a plutonium and nuclear (sometimes referred to herein as radioactivity) toxic waste storage depot and method and, more particularly, to a facility and a method for storing plutonium and nuclear toxic waste material by using a recirculating system in addition to a massive structure that is economically feasible. The invention also relates to encasement of asbestos, lead and other toxic waste by an encasing material that includes a resin and epsom salt, such as that sold under the trademark STAYTEX®, for disposal in ordinary land fills
Cross reference is made to copending, commonly owned U.S. patent application Ser. No. 08/064,548, filed May 19, 1993, entitled Environmental Non-Toxic Encasement Systems for Covering In-Place Asbestos and Lead Paint, the entire disclosure of which hereby is incorporated by reference. Cross reference also is made to U.S. Pat. No. 4,122,203, the entire disclosure of which also hereby is incorporated by reference.
The storage of plutonium and nuclear toxic waste is becoming evermore a problem. A problem with plutonium and other nuclear waste is the need to store such waste for a very long time in view of the relatively long half-life of such material. For example, some nuclear waste material have a half-life that is more than 100 years. Substantial exposure to nuclear material can be a health hazard and, in fact, can be fatal.
Monitored retrievable storage is sometimes referred to by the acronym MRS. It concerns intermediate length of time storage of waste, such as plutonium and nuclear toxic waste. It usually is considered storage of the waste for approximately 100 years or several hundred years compared to much longer term storage of, for example, 1,000 years or more.
There are four types of radiation, as follows:
a) Alpha--it often may be stopped by a sheet of paper, but it is dangerous if ingested.
b) Beta--it does not penetrate very much, but it is dangerous if inhaled.
c) Gamma--it is very penetrating and only is stopped by mass.
d) Neutrons--these are very penetrating and produce secondary gamma radiation; they are stopped most effectively by hydrogen (usually in the form of H2 O) and absorbers such as boron.
Protection of persons from unacceptable radiation doses often includes the following two considerations:
a. Prevention of direct contact of personnel with radioactive materials (e.g., contamination of clothing or skin, inhalation, or ingestion with food or water).
b. Protection against the penetrating radiations emitted by radionuclides, by the use of time limitations, distances and/or shielding.
One technique for storing plutonium and other nuclear waste has been to place the waste in a container and to bury the container. (Hereinbelow, reference to nuclear waste includes plutonium as well as other nuclear materials, especially those which emit nuclear radiation or are radioactive.) A disadvantage to this technique is the possibility that the container can rust or otherwise corrode, and the nuclear waste can leak. For example, if the nuclear waste were to leak into the ground, it could contaminate the ground water and eventually cause harm to animals, fish, vegetable life, and possibly to humans. Another disadvantage is that the radiation from the nuclear waste can too easily be emitted into the external environment causing a health hazard, for example.
Methods promoted in the past for protection against nuclear fallout depended almost exclusively on massive shielding. They were based on conventional construction methods and were the most practical and inexpensive at the time they were proposed.
One technique for shielding nuclear waste has been to provide several inches, for example, at least three inches of lead shielding, to surround the nuclear waste. Such lead shielding tends to prevent the transmission of radiation to the external environment. Another technique has been to use at least three feet of water placed between the nuclear waste and the external environment to prevent transmission of radiation to the external environment.
Storage of non-radioactive toxic waste also presents problems similar to those encountered with the storage of toxic nuclear waste. For example, if the toxic waste were placed in drums and buried, leakage due to rusting or corrosion can cause contamination of drinking water and other waters used by fish, animals and plant life.
A difficulty encountered when storing toxic waste, whether nuclear or non-radioactive, is the heat often generated during storage. Excessive heat can trigger undesirable reactions, including the possibility of explosive activity. This, of course, is undesirable, as it tends to result in a release of the toxic waste to the external environment.
One reason that nuclear waste has been buried in the ground in the past has been the good shielding provided by the ground. Also, prior above ground shelters considered for storing nuclear and other toxic waste contemplate or use concrete and metal wall and roofs; the heavy weight of the roof makes design and construction difficult and sturdiness of the structure questionable. If such structures are used, of necessity they must be small. Today there is no way permanently or substantially permanently to store large quantities of plutonium. Since 1988 over $20 billion has been spent by the U.S. Department of Energy for disposing of nuclear waste; but there has been no improvement in methods and techniques according the Secretary of the Department of Energy. However, when using the ground for shielding, a problem is encountered in the case of a spillage, leak, etc. of the primary containment medium, such as a metal drum or the like.
Another problem with heavy weight roof designs for a structure that would provide such shielding is the increased possibility of collapse from earthquake forces or the like. It would be desirable to reduce the likelihood of such damage due to earthquake or the like.
Encasement using STAYTEX® material can be used for asbestos, lead, etc. for disposal in ordinary landfills. An example of such encasement is described in commonly owned pending U.S. patent application Ser. No. 08/064,548 filed May 19, 1993.
With the foregoing in mind, it will be appreciated that improvements in storage of toxic waste, both of the nuclear type and the non-radioactive type are desired.
An aspect of the invention relates to the use of a fluid material, such as a slurry, which contains a material intended to receive and to collect nuclear radiation, while preferably also blocking transmission of the nuclear radiation, and precipitating out such material from the fluid material for subsequent storage of the precipitated material.
An exemplary material contained in the fluid or slurry mentioned in the preceding paragraph is epsom salt; and, therefore, an aspect is the use of epsom salt as summarized in the preceding paragraph.
Other exemplary materials contained in the slurry or other carrier fluid include Na2 B4 O7.10H2 O and CoSO4.7H2 O, and an aspect is the use thereof as summarized in the paragraphs above. Still other materials may be used in the slurry or fluid carrier, as are described for use herein and equivalents thereof, and, therefore, the same are aspects hereof.
Another aspect of the invention relates to a toxic waste storage depot where toxic waste can be stored, including a building have a portion located below ground, walls for bounding an interior space in the building, and fluid for removing thermal energy from the building and for providing radioactive shielding, at least as a part of the building.
According to another aspect of the invention, a toxic waste storage depot uses the shielding effect of the ground to tend to prevent leakage of radiation in combination with a fluid of specific gravity characteristics greater than those of water to provide both radioactive shielding and thermal energy removal functions.
A further aspect relates to the use of fluid, such as water, in combination with epsom salt or MgSO4.7H2 O or another material as disclosed herein and equivalents thereof to provide relatively high specific gravity slurry material to effect radiation shielding and thermal energy removal from a toxic waste storage facility.
An aspect of the invention relates to a method of effecting radiation shielding and thermal energy removal from a toxic waste storage facility including using water in combination with epsom salt or another material as disclosed herein and equivalents thereof to provide relatively high specific gravity slurry material to block transmission of radiation and to remove thermal energy.
Another aspect relates to a method of removing radioactivity from the interior of a building by transporting radioactive material within a slurry and filtering out the then contaminated material outside the building, thus removing it in a continuous fluid recirculation system.
A further aspect relates to a toxic waste storage facility including a building having a portion located below ground level, walls for bounding an interior space in the building, and fluid for removing thermal energy from the building and for providing radioactive shielding at least at part of the roof of the building.
An additional aspect relates to a toxic waste depot method including using the shielding effect of the ground to tend to prevent leakage of radiation in combination with a fluid of specific gravity characteristic greater than that of water to provide both radioactive shielding and thermal energy removal functions.
Yet another aspect relates to a method of disposing of toxic material, such as asbestos, lead, and the like, including encasing the toxic material in a cured resin system including at least one liquid thermosetting resin having particulate solids dispersed therein, about 100% of the solids having a U.S. Standard mesh size of about 225 mesh or smaller and at least about 10% of the solids having a U.S. Standard mesh size of about 325 mesh or smaller, wherein the solids comprise crystalline hydrated inorganic salts, and placing the encased material in a conventional land fill.
An aspect of the present invention relates to a prefabricated building system, which offers possibilities for incorporating a reasonable degree of radiation protection (containment) by optimizing the time, distance and shielding parameters while, at the same time, recognizing the importance of cost effectiveness.
Another aspect relates to using a water solution or slurry of soluble and/or insoluble salts, such as magnesium sulfate heptahydrate (MgSO4. 7H2 O), sodium borate decahydrate (Na2 B4 O7.10H2 O) and/or cobalt sulfate heptahydrate (CoSO4.7H2 O) to remove heat, to block radiation, and/or to remove radiation in a toxic waste storage facility and method; and another aspect relates to including other chemicals, such as boron salts (for example, sodium metaborate and boric acid crystals) in the solution or slurry; and/or another aspect relates to using in the water solution and/or slurry high neutron cross-section materials, such as lithium, boron, and/or cobalt.
Another aspect relates to including in the water solution or slurry metallic fines, such as lead and/or iron.
Another aspect relates to using the foregoing materials to scatter radiation in order to effect neutralizing thereof.
Another aspect relates to the inclusion of water molecules, plastics, and/or hydrogen containing materials as part of a panel construction useful as a wall, ceiling or floor of a toxic waste storage facility in which radiation is to be contained in order to block transmission of or to shield the radiation.
Another aspect relates to the forming of a liquid solution or slurry with a salt or other material to remove heat, to block radiation transmission, and/or to remove radiation, directing the solution or slurry through portions of a building or the like, and subsequently adding an ingredient to the solution or slurry to precipitate out the salt for removal and storage thereof, including radiation therein.
Another aspect relates to the use of water in a solution or slurry with one or more ingredients to remove heat, to block radiation, and/or to remove radiation in a toxic waste facility.
Another aspect relates to the use of a prefabricated building structure including replaceable panels to form a toxic waste storage facility, and yet another aspect includes forming such structure of steel with replaceable panels in order to make the structure substantially earthquake proof.
Another aspect relates to the developing of energy output from a toxic waste storage facility including at least one of using solar energy to provide electrical power for the facility and/or generating electric energy from heat removed from the facility with toxic waste stored therein.
Another aspect relates to the monitoring of one or more conditions of a toxic waste storage facility in which radioactive material and/or other material is stored using detectors and other instrumentation molded into prefabricated walls and a further aspect relates to using the information from such detectors and/or instrumentation to monitor such condition(s) and/or to provide control function(s), such as, for example, air circulation, liquid circulation, material contained in a water solution and/or slurry used to remove heat, to block radiation, and/or to remove radiation.
Another aspect relates to MRS for plutonium and other nuclear toxic waste and facilitating off-site monitoring of the storage facility for inventory purposes, for preventing theft, and/or for other purposes.
Another aspect relates to a toxic waste storage facility and method in which a water solution and/or slurry flows through pipes contained in one or more walls, ceilings or floors to remove heat, to block radiation, and/or to remove radiation, such that the fluids flow generally from the top of the facility toward the bottom to avoid clogging of pipes or settling out of solid material contained in the solution and/or slurry.
These and other objects, aspects, features and advantages of the present invention will become more apparent as the following description proceeds.
To the accomplishment of the foregoing and related ends, the invention, then, comprises the features hereinafter fully described and particularly pointed out in the claims. The following description and the annexed drawings setting forth in detail a certain illustrative embodiment of the invention. This embodiment is indicative, however, of but one of the various ways in which the principles of the invention may be employed.
Although the invention is shown and described with respect to a certain embodiment, it is obvious that equivalents and modifications will occur to others who have ordinary skill in the art upon reading and understanding the specification. The present invention includes all such equivalents and modifications and is limited only by the scope of the claims.
In the annexed drawing:
FIG. 1 is a schematic side elevation section view of a plutonium and nuclear toxic waste storage depot in accordance with the present invention;
FIG. 2 is a schematic illustration of an area of the sidewall of the depot building of FIG. 1;
FIG. 3 is a schematic isometric view, partly in section, of a wall, floor, or ceiling panel used in the depot building of the invention;
FIGS. 4 and 5 are schematic plan views of the panel of FIG. 3 showing series and parallel piping arrangements, respectively;
FIG. 6 is a schematic edge elevation view of such panel having concrete and brick facing material on respective faces thereof;
FIG. 7 is a schematic edge elevation view of such panel having concrete and metal facing material on respective faces thereof;
FIG. 8 is a schematic view of a process line for making panels of the invention;
FIGS. 9, 10 and 11 are respective graphs identifying characteristics of a slurry material of water and epsom salt used in accordance with the invention;
FIG. 12 is a schematic top plan view of a door to the depot building of FIG. 1 of the invention;
FIG. 13 is a schematic illustration showing a process of the invention wherein the epsom salt or other ingredient contained in the slurry is to be mixed with a precipitating ingredient or agent in order to remove the salt from the liquid;
FIG. 14 is a schematic illustration of a control system for controlling ingredients, flow, and/or the like in response to a characteristic, such as temperature or the like detected, for example, at the waste storage facility; and
FIG. 15 is a schematic illustration of a prefabricated building structure useful in constructing the toxic waste storage facility of the invention.
Referring to the drawings, wherein like reference numerals designate like parts in the several figures, and initially to FIG. 1, a toxic waste depot in accordance with the present invention is generally indicated at 10. The depot 10 is in the form of a building 11 that is located at least partly in the ground 12. The building 11 has an interior space 13 in which waste material 14 may be stored in a storage location 15. The storage location 15 preferably is located well below the surface 16 of the ground 12 in order to take advantage of the radiation shielding capability of the ground. The size of the storage location 15 in space 13 is suitably large to store a desired amount of radioactive material. Part of the storage location near ground level or above ground level may be used for toxic non-radioactive material, such as asbestos encased in STAYTEX® material. The building 11 also includes a fluid flow system generally designated 17 through which a fluid is conducted. The fluid is intended to provide both radiation shielding effect when necessary, and thermal energy removal, as is described in greater detail below. Also, the fluid provides for relatively easy removal and convenient storage of radiation-containing or radiation contaminated material therefrom.
As is described in further detail below, the flow system 17 carries a fluid through portions of the building 17, such as the walls, roof, floors, etc. The fluid, for example, is a slurry. The fluid, for example, includes ingredients that contribute to the radioactive energy shielding by scattering, reflecting or otherwise reducing the energy of radioactive waves or particles. The energy reduction may result in transfer of heat energy to the slurry and the slurry preferably is well suited to transport the heat energy for subsequent removal thus avoiding excessive heat accumulation in the building. As such, the fluid may be used as a secondary coolant for all types of nuclear reactors.
Generally, each time a radioactive wave or particle is scattered or reflected by an ingredient in the slurry, the wave or particle loses energy, usually that loss is in the form of heat, or in any event energy is reduced. Since such energy usually is lost as heat, such heat can be removed by the flowing slurry. Preferably an ingredient in the slurry includes water molecules, which are particularly useful to absorb heat; and as is described in greater detail herein, such water molecules may be part of an hydrated salt, such as epsom salt, or other material.
Each "scattering reaction" or event will result in departing photons from the wave or particle of radioactive energy. The energy released due to departing photons resulting from a particular scattering event usually will be less than the energy released during a prior scattering event or the original photon release. Therefore, energy is depleted from the radioactive wave or particle. When a scattering interaction takes place in a wall, the most likely paths for the photon to exit the wall is the shortest path from the scattering interaction to the surface of the wall. However, since the slurry continues to move during such events, there is in effect a moving wall which continues to absorb energy and to encounter and/or to cause additional scattering events further to deplete or to dissipate the energy from the radioactive wave or particle.
Preferably the epsom salt or other equivalent ingredient, such as those described herein, is heavily loaded in the slurry, e.g., including a maximum amount dissolved in the carrier medium, which may be water or other fluid. The characteristic of solubility of the epsom salt in the water facilitates maximizing the loading of epsom salt in the water; however, solubility of the epsom salt or other material in the carrier medium is not a requirement of the broad principles of the invention.
Additionally, since the slurry is flowing in the flow system 17, it provides a "moving target" to effect such reflection and scattering. Also, to enhance such reflection and scattering, the slurry may include reflective material, an example of which is metal fines.
Briefly, The hydrate salt of the invention in effect is a heat sink, which functions to absorb energy, especially thermal energy. The relatively high water content of the hydrate helps to improve the heat sink function. The slurry used in the invention is in pumpable form; the preferred slurry is a hydrate salt in a liquid. The metal fines enhance scattering or reflection effect; preferably the fines are a relatively heavy material to accomplish the desired result, although other materials may be used for such purpose.
The toxic waste depot 10 includes a large hole or open pit opening 20 formed in the ground 12. Preferably adequate clearance and thickness of ground material, earth, etc. is located around the large hole 20 to provide adequate support for the building 11 and adequate shielding for radioactive energy. It has been found in the past that three feet of dirt often is adequate to provide satisfactory shielding of radiation. Additional thickness may be required in some circumstances; and possibly a thinner layer also may be adequate, depending on circumstances. There should be adequate support capability by the ground 12, including the base 21 of the large hole 20 to support the building 11. If necessary, additional footers (not shown) may be used to provide the desired support. Also, pipes 23 in the walls and roof of building 11 provide reinforcement to help make them structural.
The large hole 20 is lined by a liner 22. An exemplary liner 22 may be of heavy duty plastic or rubber material used conventionally to line the bottom of convention toxic waste storage facilities. The liner 22 should have adequate strength to avoid tearing, and it should have adequate fluid impermeability characteristics to avoid leakage. An exemplary liner material is that sold by Reef Industries, Inc. of Houston, Tex. under the designation of PERMALON PLY X-210. Preferably the liner 22 extends side-wise beyond the building 11 a distance adequate to tend to prevent water from the directly flowing into the ground 12 directly adjacent the building 11. Such side-wise extensions 23, 24 protecting the ground areas 25, 26, respectively are seen in FIG. 1. Such extensions 23, 24 preferably fully circumscribe the building 11 for the described purpose, and by preventing water flow adjacent the sidewalls of the building 11, the tendency of the water to become radioactive and to leak into the water table and other water supplies is reduced. A catch basin and/or sump 26 may be provided outside the building 11 to collect material from an emergency spill; a pump may be provided to pump such collected material for further treatment, storage and/or disposal.
The building 11 has a floor 30, sidewalls 31, and a roof 32. The top plan view of the building 11 may be circular, rectangular, hexagonal, or some other shape, depending on the shape of the large hole 20, the layout of the sidewalls 31, etc. The exposed above ground portion 31 a of the sidewalls 31 and the roof 32 preferably are adequately thick to contain at least a portion of the fluid flow system 17. The below ground level portion 31b of the sidewalls 31 may be thinner than the portions 31a, as it may be unnecessary to have fluid flow system 17 therein or the extent of such fluid flow system therein may be less than is required in the portion 31a and roof 32. Specifically, since the fluid flow system 17 provides both radioactive energy shielding and thermal energy removing function, for the portion of the fluid flow system 17 that is not within the ground 12, a larger capacity of fluid is required. However, for that portion of the building 11 within the ground 12, radioactive energy shielding is provided at least in part by the ground itself, and, therefore, the extent of need for shielding provided by the fluid flow system 17 is reduced. However, it may be that some shielding is desired by the fluid flow system 17 in the below ground portion 31b of the sidewalls 31, and it also may be that thermal energy removal is desired in the portion 31b, too. The floor 30 is well below the surface 16 of the ground 12, and, therefore, shielding function of the fluid flow system 17 also may be unnecessary there. However, it may be desirable to have thermal energy removal function provided by the fluid flow system 17 in the floor 30.
The building 11 preferably is several stories tall including about one story located above ground and several stories located below ground surface level, for example, at least three stories below ground. Each floor is made of structural prefabricated panels that are light weight compared to heavy concrete panels. Actual weight of a given panel may depend on whether the panel is used above ground or underground. The floor panels also include pipes in them to provide structural capability. The pipes are intended to carry the slurry described below to provide further shielding function. Since shielding is provided by the floors intermediate the bottom floor and the roof, the shielding function or burden required to be provided by the roof is reduced; and this reduces the thickness and other size and structure requirements of the roof. Such structure takes advantage of the shielding capacity of the ground 12 and also can take advantage of the support provided by the ground 12 reinforcing the sidewalls 31b located within the hole 20. The sidewalls 31 provide support for the roof 32. The sidewalls 31 and the floor 30 provide containment for the solid and liquid materials in the space 13 of the building 11. Furthermore, the sidewalls 31, floor 30 and roof 32 may include space to contain part of all of the fluid flow system 17. For example, a plurality of pipes may be located in the walls, floor and/or roof to conduct a slurry through the pipes for the described purpose of shielding and thermal energy removal. Pipes 23, also provide the structural integrity of the walls and roof. Concrete is too heavy for practical use for large structures (buildings) that are capable of radioactivity shielding. Three feet or other relatively large thickness of concrete is needed to provide adequate shielding would be so heavy that it would be difficult at best, and in cases impossible, to provide adequately strong side walls and reinforcement in the roof to support such a concrete roof.
The walls 31, floor 30, and roof 32 may be formed of various materials. Preferably, though, the walls, floor and roof are formed in part by a material sold under the U.S. Registered Trademark STAYTEX®. An example of such STAYTEX® materials and methods of using it are disclosed in U.S. Pat. No. 4,122,203. Additional description of such material and methods of using it are described in copending, commonly owned U.S. patent application Ser. No. 08/064,548, filed May 19, 1993, entitled Environmental Non-Toxic Encasement Systems for Covering In-Place Asbestos and Lead Paint. The STAYTEX® material may provide both facing or surfacing functions as well as sealing functions. The STAYTEX® material may be sprayed onto joints between pre-fabricated panels making up the sidewalls 31, floor 30, or roof 32, for example, in the manner illustrated in FIG. 2.
Briefly referring to FIG. 2, a plurality of pre-fabricated wall panels 33 are illustrated. The panels may be made of the following materials and/or by the following methods.
An exemplary wall panel 33 is illustrated in FIGS. 3-7. The wall panel 33 includes pipes 23, for example of steel, polyvinyl chloride (pvc), or other metal, plastic material or other synthetic or natural material. A core material 34 of a panel is made of the mentioned STAYTEX® material 34a, preferably in combination with fiberglass sheets 34b. The STAYTEX® material can be molded or sprayed relative to the pipes to form therewith an integral structure. The fiberglass may provide reinforcement and a base to which the STAYTEX® material easily can adhere.
An exemplary manufacturing line 35 to manufacture the panels 33 is illustrated schematically in FIG. 8. To make a panel, the pipes 23 are connected in the manner desired for structural and fluid carrying purposes. The fiberglass sheets 34b are placed relative to pipes 23 on a conveyor 35a for carrying to a spray booth 35b and then to a mold 35c. The STAYTEX® material is applied to the pipes and fiberglass, e.g., in the spray booth 35b to make an integral structure thereof, particularly after the STAYTEX® material has cured to solid relatively rigid form. The STAYTEX® material may be applied by spraying, troweling, roller coating, etc. The panel may be heated at the infrared heater 35d to complete or to expedite curing. The panels may be shaped during molding by using a specifically shaped mold and/or molding press 35d to shape the panel during the formation of the panel.
The pipes 23 may be arranged in a plurality of horizontal or vertical rows or in some other pattern in the panel 33. The pipes 23 may be connected for serial flow (see FIG. 4) of slurry through a panel; they may be connected for generally parallel flow (see FIG. 5) of slurry through a respective panel 33 or through plural panels (the latter case being where plural pipes of one panel are connected to plural pipes of another panel). One or more nipples 36 or other pipe connectors is exposed from each panel for connection to the flow system of the invention, i.e., to the pipes in another panel, to another portion of the flow system, etc.
The wall panels, floor panels and roof panels may be identical. Where needed, additional facing or skin material to prevent damage to the panels and/or to provide particular characteristics to the panels may be used. Exemplary outer skin material include steel, brick, various natural and/or synthetic materials, composite materials, etc. In FIG. 6 is illustrated schematically a panel 33 with concrete facing material 33a, e.g., for contact with the earth of the large hole 20, and with brick facing material 33b, e.g., for exposure inside the building 11, say as the inside wall or top surface of a floor on which a vehicle easily may travel. In FIG. 7 is illustrated schematically a panel 33 with concrete facing material 33a, e.g., for contact with the earth of the large hole 20, and with steel facing material 33c, e.g., for exposure inside the building 11.
At the seams 36 between adjacent panels 33 STAYTEX® material may be applied, for example, by spraying, troweling, roller coating, etc. to seal the joints. The STAYTEX® material also may be used to provide a sealing function between the sidewalls 31 and the floor 30 and/or roof 32 as well as between other portions of the overall structure of the building 11.
Referring to the fluid flow system 17, a plurality of pipes 23 are located in the roof 32, in the sidewalls 31, including both the portions 31a, 31b, and in the floor(s). A liquid slurry 41 flows through the pipes 23, preferably being pumped therethrough by pumping equipment 42. The pumping equipment may include one or more standard water pumps, outside the building 11, either above ground, in ground, for example in a sump 42, and/or in a treatment system 43 located in the space 13 of the building 11 and/or outside the building. There may be one or more treatment systems and/or parts thereof, and each may be located inside or outside building 11. The sump 42 may be separate from, the same as, or a part of the sump or catch basin 26. A filter system 44 also is provided in the treatment system 43 to filter excessive radioactive material from the slurry 41, to filter other particular material from the slurry 41, and to provide such removed material to a storage container 46 for storage in the storage location or area 15 (FIG. 1).
The slurry 41 in the pipes 23 preferably has a relatively high specific gravity compared to the specific gravity of water, which is 1. Exemplary relatively high specific gravity is from about 1.2 to about 1.6. Other relatively high specific gravities also may be used for the slurry 41. A specific gravity of 1.6 is obtainable by making a slurry of water and a relatively high concentration of epsom salt, as is elsewhere described herein. A slurry of water and boron also may be used.
The slurry may contain water and a metal salt hydrate. The metal salt hydrate generally has the following formula:
Mx Yz.nH2 O
in the formula, M represents a metal. X represents the number of metal atoms in a metal salt hydrate molecule. X is generally a number between about 0.5 and about 10, and preferably about 1 to about 5. Y is a salt. Z represents the number of salt components in the metal salt hydrate molecule. Z is generally a number from about 0.5 to about 10, and more preferably about 1 to about 5. n is the amount of water contained in the metal salt hydrate molecule. n is from about 0.5 to about 20. More preferably, n is about 1 to about 15, and even more preferably, n is about 2 to about 10.
The relative amount of metal salt hydrate included in the slurry is any amount so long as the slurry is in a liquid or semiliquid state so that it may be circulated throughout the structure, or through the pipes. In one embodiment, the amount of metal salt hydrate added to water is governed by the resultant specific gravity of the slurry.
The metal of the metal salt hydrate may be any metal capable of forming a metal salt hydrate. For example, the metal may be an alkali metal, an alkaline earth metal, a transition metal or another metal. Examples of alkali metals include Li, Na, K, Rb, Cs and Fr. Alkaline earth metals include Be, Mg, Ca, Sr and Ba. Transition metals include Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Os, Ir, Pt, Hg and Au. Other metals include Al, Ga, Ge, In, Sn, Sb, TI, Pb, Bi and Po. In a preferred embodiment, the metal of the metal salt hydrate is selected from Al, Ca, Co, Cu, Mg, Ni, Na and Zn.
The salt component is any salt capable of forming a metal salt hydrate. Examples of salts include sulfate, nitrate, chloride, bromide, acetate, borate, metaborate, carbonate, hydrogen phosphate, bicarbonate, and thiosulfate. Preferred embodiments of the salt include sulfate, borate and metaborate salts.
Specific examples of the metal salt hydrate include Al2 (SO4).18H2 O, CaCl2.2H2 O, CaCl2.6H2 O, Ca(NO3)2.4H2 O, CaSO4.0.5H2 O, CaSO4.2H2 O, CoSO4.7H2 O, CuCl2.2H2 O, Cu(NO3)2.3H2 O, CuSO4.5H2 O, MgBr2. 10H2 O, Mg(NO3)2.6H2 O, MgSO4.7H2 O, NiOAc.3H2 O, NiSO4.7H2 O, NaOAc.3H2 O, Na2 B4 O7.10H2 O, Na2 CO3.10H2 O, Na2 HPO4.12H2 O, Na2 SO4.10H2 O, Na2 S2 O3.5H2 O and ZnSO4.6H2 O (OAc=acetate).
The slurry may also contain fines. Fines are small metallic particles capable of being dispersed in the slurry. The fines enhance the scatter effect of the slurry. The amount of fines in the slurry is any amount such that the metallic fines remain substantially dispersed in the slurry. Fines may be made of heavy metallic particles. Examples of heavy metallic particles include iron fines, nickel fines, copper fines, zinc fines, palladium fines, silver fines, tin fines, antimony fines, platinum fines, gold fines and lead fines. In another embodiment, the fines may be an alloy made of one or more of the heavy metallic particles listed above. Although the size of the fines is not critical, the size should be appropriately large to deflect (or otherwise suppress) radiation, and not too large or too small so as to cause packing or clogging of the slurry. The size of the metallic particles may be from about 25 mesh to about 200 mesh. In a preferred embodiment, the size is from about 50 mesh to about 100 mesh.
A preferred exemplary material for use to raise the specific gravity of the slurry is epsom salt. In particular, it has been found that water containing up to about 30% epsom salt will have a specific gravity of about 1.2. Thirty percent is about the maximum amount of epsom salt that can be held in slurry in water without having to elevate the water temperature. However, higher concentration will be used by raising temperature of the slurry to try load the slurry with as much epsom salt as possible. See the graphs of FIGS. 9-11 for data regarding composition and characteristics of such slurries of water and epsom salt. For example, at a temperature of 36° C. the specific gravity is about 1.35 for 30% MgSO4 by weight. As an example, the slurry is formed by mixing epsom salt with water and elevating the temperature of the mixture to increase the amount of epsom salt that can be dissolved in the water than that possible at usual room ambient temperature. The slurry also can contain solid particles of epsom salt. The percent of salts are regulated by the temperature of the slurry to maintain maximum salt levels for most efficient operation. The radiation level is monitored by a conventional monitor 48 located in the treatment station 43 and/or elsewhere in the building 11 or even outside the building 11, for example, and by adjusting the temperature of the slurry proportionally to the radiation level, salt level can be increased or decreased as a function of radiation. Preferably such proportion is in direct proportion, although such direct proportion may be nonlinear. Such temperature control and salt level can be increased or decreased as a function of radiation. Such temperature control and salt level are adjusted by operation of the heat exchanger 45, for example, which is described hereinbelow.
The use of 30% epsom salt in the water tends to reduce the freezing point of the water to about 0° F. This feature advantageously helps to avoid the possibility of the slurry 41 freezing in the pipes 23. Continuous circulation of the fluid in the pipes under the influence of the pump 42 also helps to avoid freezing. Furthermore, thermal energy generated in the building 11 by the toxic waste stored therein also helps to avoid freezing of the solution.
By using a slurry 41 that has a relatively high specific gravity, the shielding effectiveness of the slurry is enhanced. Therefore, the thickness of the roof 32 does not have to be a full three feet, which is the thickness necessary if water alone were used for radiation shielding purposes.
Preferably the epsom salt dissolves in the carrier medium e.g., water, of the slurry. However, solubility is not a requirement. Solubility usually increases the amount of epsom salt or other ingredient that can be loaded into the slurry. Some or all of the epsom salt or other ingredient in the slurry may be undissolved or even not soluble in the carrier medium.
It is noted that sodium chloride and other salts would not be particularly useful for the function provided by the epsom salt. Sodium chloride is corrosive and would tend to destroy the pipes 23 and/or other portions of the depot 10. Epsom salt, on the other hand, is not corrosive and is non-toxic.
Exemplary materials which may be useful in the invention are presented in Table I and Table II below. The tables present solubility data. Preferred characteristics of the materials presented in the tables include solubility in the carrier medium, e.g., aqueous solution, and water of hydration molecules for the absorption of heat energy.
Many inorganic salt hydrates can be utilized as heat storage or heat pump materials by undergoing a change in the degree of hydration. Table I presents data on solubility and specific gravity of common salt hydrates in aqueous solution. Where possible, tables of solubility as a function of temperature and specific gravity as a function of composition have been included. Table II presents data on solubility of common salt hydrates in aqueous solution at other temperatures.
TABLE I______________________________________Common inorganic salt hydrates HYDRATE SOLUBILITYaMETAL SALT FORMULA cold hot S.G.______________________________________aluminum sulfate Al2 (SO4).18H2 O 86.900 1104100 1.77calcium chloride CaCl2.2H2 O 97.70 32660 0.835calcium chloride CaCl2.6H2 O 2790 53620 1.71calcium nitrate Ca(NO3)2.4H2 O 2660 66030 --calcium sulfate CaSO4.0.5H2 O 0.320 sl s -- CaSO4.2H2 O 0.241 0.222100 2.30- 2.37cobalt sulfate CoSO4.7H2 O 60.43 6770 1.94825copper chloride CuCl2.2H2 O 110.40 192.4100 2.54copper nitrate Cu(NO3)2.3H2 O 137.80 1270100 2.3225copper sulfate CuSO4.5H2 O 31.60 203.3100 2.28magnesium bromide MgBr2.10H2 O 3160 vs 2.00magnesium nitrate Mg(NO3)2.6H2 O 125 vs 1.636325magnesium sulfate MgSO4.7H2 O 7120 9140 1.675-1.679nickel acetate NiOAc.3H2 O -- -- 1.744nickel sulfate NiSO4.7H2 O 75.615.5 475.8100 1.948sodium acetate NaOAc.3H2 O 76.20 138.850 1.45sodium borate Na2 B4 O7.10H2 O 2.010 170100 1.715sodium carbonate Na2 CO3.10H2 O 21.520 421104 1.4415sodium hydrogen Na2 HPO4.12H2 O 4.15 87.434 1.52phosphatesodium sulfate Na2 SO4.10H2 O 110 92.730 1.490sodium thiosulfate Na2 S2 O3.5H2 O 79.40 291.145 1.72917zinc sulfate ZnSO4.6H2 O s 117.540 1.978______________________________________ a Units: solubility gram per 100 cc temperature °C. s -- soluble sl -- slight soluble vs -- very soluble superscripts indicate the temperature of measurement
TABLE II______________________________________Common inorganic salt hydratesSolubility Data at Other Temperatures Temp., °C.Metal Hydrate superscripts indicateSalt Formula References______________________________________calcium chloride CaCl2.2H2 O 25 CaCl2.6H2 O 20, 25, 50, 180cobalt sulfate CoSO4.7H2 O 25copper chloride CuCl2.2H2 O 25copper sulfate CuSO4.5H2 O 25, 50, 75magnesium sulfate MgSO4.7H2 O 10-50, 40, 50nickel sulfate NiSO4.7H2 O 10, 20, 40sodium acetate NaOAc.3H2 O 20sodium carbonate Na2 CO3.10H2 O 0, 20, 25 30, 60, 90sodium hydrogen Na2 HPO4.12H2 O 25phosphatesodium sulfate Na2 SO4.10H2 O 0, 25zinc sulfate ZnSO4.6H2 O 25, 40, 50______________________________________
It is a purpose of the fluid flow system 17 to control the temperature in the space 13 of the building 11. For this purpose a heat exchanger 45 in the treatment center 43 receives fluid from the filter 44 and is able to cool the fluid and to transfer the thermal energy thereof to the environment external of the building 11. Heat from the heat exchanger is an energy source to use for other purposes, such as heating and cooling building 11, another building, or form some other purpose. The treatment center 43 may be located either inside or outside of the building 11; part may be in each location; or part or all of the treatment center may be redundantly located both inside and outside the building 11. An advantage to locating the heat exchanger or part of it outside the building is to use outside ambient temperature and/or supplemental heating or cooling provided there to control salt loading or salt level of the slurry.
The shielding effectiveness of the slurry 41 in the pipes 23 of the fluid flow system 17 preferably is approximately equivalent to the shielding effectiveness of about three feet of water and/or approximately equivalent to about three inches of lead shielding. However, the weight of the lead shielding, the environmental hazard of the lead in general, the weight and containment requirements for three feet of water, and so on are not required in the present invention. Rather, the pipes 23 may be included within the roof 32 and the exposed above ground sidewalls 31a. Pipes 23 of the fluid flow system 17 also may be included in the below ground portions 31b of the sidewalls and/or in the floor 30. Further, the pipes 23 may be used to conduct slurry 41 in other places in the building 11 for the purpose of generally controlling the temperature in the building. The thickness of the below ground portions 31b of the sidewalls and the thickness of the floor 30 need not be as great as the thickness of the roof 32 or of the above ground portion 31a of the sidewalls, since the ground 12 can be relied on to provide shielding function, as was described above.
In operation of the toxic waste depot 10, then, waste, such as toxic waste in general, radioactive waste in particular, etc. may be stored in the building. The pump 42 pumps slurry 41 through the pipes 23 of the fluid flow system 17. The slurry tends to prevent leakage of radiation through the roof 32 and above ground portion 31a of the sidewalls. The epsom salt in the slurry tends to absorb radiation. The ground 12 tends to prevent leakage of radiation to the above ground external environment or to the external environment more than several feet away from the building 11. The slurry 41 tends to remove thermal energy (heat) from the interior space 13 of the building in order to control the temperature therein. The excess heat can be conducted by the heat exchanger 45 to the environment external of the building 11 or to some other location without contaminating the external environment.
The filter 44 may be used to remove radioactive material, e.g., the epsom salt or equivalent and/or similar functioning material, from the slurry 41 and/or particulates from the slurry 41 as waste. Such waste may be placed in drums or otherwise delivered to the storage area 15 in the space 13 of the building 11.
In the filter 44 of the treatment plant 43 the slurry is cooled to cause the contaminated salt particles to drop out. The contaminated solid particles can be filtered from the slurry and then can be processed for detoxification and/or they can be stored. For such storage, for example, a settling pit 49 can be used to store the particles. Such a settling pit 49 is depicted schematically in FIG. 1. The settling pit may have at least three feet deep of water as a shield for blocking upward emission of radiation.
The slurry can be pumped into the settling pit 49, and the settling pit can serve a filtering function in addition to or alternatively to the filter 44. The slurry will remain below the water level due to the larger specific gravity of the slurry. The contaminated salt particles will precipitate out to the bottom of the pit by maintaining the temperature of the pit relatively cool, e.g., sufficiently cool to effect such precipitating function. The remaining slurry which is substantially uncontaminated can be removed from the settling pit; subsequently loaded as much as possible with epsom salt; and pumped through the flow system 17 again.
A door 50 provides an access to the interior space 13 of the building 11. The door 50 may be made of the same type of material of which the above ground portion 31a of the side walls is made and preferably the door also includes a portion of the fluid flow system 17 to provide for radiation shielding and for temperature control functions. The height of the door 50 preferably is adequate to provide, when open, access to a forklift vehicle or other vehicle that is used to carry into the space 13 fifty-five gallon drums 46 of toxic waste or some other size containers for storage within the space 13 of the building 11.
A top plan view of the door 50 is shown in FIG. 12. The door 50 preferably includes one or a plurality of baffle walls which provide a circuitous route into the interior 13 of the building 11 while preventing a direct path for radiation leakage through the door. As is seen in FIG. 12, the door includes an outer door 50a in the outer wall 50b, which is comprised of panels 33, for example. The outer door 50a can be opened for access to the building interior 13 or closed. A baffle wall 50c blocks a direct path into the building interior from the door 50a. The interior wall 50d has an opening 50e which provides direct entrance to the interior 13. The space 50f between the walls 50b, 50c, 50d is a circuitous path between the outside ambient environment and the interior of the building. The size of the space 50f preferably is adequate for a vehicle to drive therealong in order to carry waste, containers, or equipment into or from the building. Each of the walls 50b, 50c, 50d is made of a plurality of the panels 33.
An elevator 51 includes an elevator shaft 52 and an elevator car 53 for transporting the forklift truck and/or the waste as well as individuals between various levels in the building 11. Also, a ramp 54 is provided to enable the forklift truck and/or individuals to drive or to walk between levels of the building 11. A floor 55 part way across the building or across the entire building is provided for various storage, equipment, and/or other functions as may be desired. Racks 47 for storing drums 46 or other material may be provided on one or more floors. The racks also may be used to store encased asbestos, lead painted objects, or other material.
In using the toxic waste depot 10 to store radioactive material, the radioactive material preferably is stored at the lowest levels of the building. The radiation tends to emit horizontally and perpendicularly in straight lines through the walls into the ground. The ground is a good shield and prevents the radiation from reaching other sources of water, etc. The fluid system 17 also may reduce such radiation that is emitted into the ground, depending on the extend to which slurry 41 is located in the side walls which are below ground. That radiation which tends to emit vertically is finally blocked by the slurry 41 flowing through the pipes 23 in the fluid flow system in the roof 32. Temperature in the space 13 of the building 11 is controlled by the fluid flow system and the heat exchanger 45 associated therewith so that the possibility of dangerous conditions due to high temperature in the building is avoided.
The radiation blocking and/or absorbing function of the floors of the building 11, especially the ones intermediate the bottom floor and the roof, also reduce the radiation blocking and/or shielding requirement of the roof 32. This allows the roof to have a practical thickness that will be both efficient and economical. That is, the roof can be of reduced thickness, mass, etc., compared to the requirements for roofs in prior primarily concrete storage facilities.
The building 11 provides a storage facility for nuclear and other toxic waste. The waste may be stored in drums 46. The waste and/or drums 46 may be stored in racks 47, if desired. Contaminated equipment from a dismantled nuclear plant or from a refurbished nuclear plant also may be stored in the building 11 either in a drum, on a rack, or placed on the floor of the building. Since the bottom floor 30 has maximum direct support, e.g., from the earth beneath, it is desirable to place heavier material on the bottom floor and to place less heavy material on the upper floor level(s) 55.
Additionally, as was mentioned above, the building 11 provides a place for storage of asbestos, objects painted with lead paint and/or other types of materials which have been encased in STAYTEX® material according to the disclosure of U.S. patent application Ser. No. 08/064,548. However, alternatively such encased materials can be placed directly in a conventional land fill.
The building 11 of the present invention preferably is of a modular design in that multiple panels can be used to form walls, floor and ceiling thereof. Preferably the building 11 is provided with gravity ventilation and with anti-corrosive coatings, where needed. Desirably the height between floor and ceiling permits double stacking of drums or other storage containers. Seismic tie-downs may be provided for securing the building in the event of a tremor. Concrete underground structures are suspect; they may crack. The building of the present invention using panels 33 in walls, floors and ceiling/roof is more flexible than concrete and is less subject to damage due to earth tremors than conventional concrete structures.
Other features includable in the building 11 of the invention include a fire suppression system. Desirably the various fixtures are explosion proof, such as the mechanical equipment, ventilation equipment, lighting, and HVAC system. The various parts of the building may be non-combustible having a fire rating of 1 to 4 hours. Sprinkler systems and monitoring systems for fire, gas, etc. may be provided. Exemplary toxic gas monitoring products are sold by Kem Medical Products Corp. The sumps described preferably are segregated for security and backup; and walls may be provided in the building to separate various portions. The building may be temperature controlled using appropriate HVAC equipment, and may take advantage of the heat exchanger 45 and flow system 17 of the invention, if desired. Further, if desired FM explosion relief panels may be used in the building.
It will be appreciated that in the present invention an improved building structure provides a storage depot for plutonium and nuclear waste, for example. A fluid circulation system may provide temperature control for the storage depot and also blocks transmission and absorbs nuclear radiation. Such nuclear radiation absorption may be in epsom salt which is loaded into the fluid to form a slurry. The epsom salt may be removed from the slurry and subsequently stored in the building. The fluid can be re-loaded with epsom salt for further circulation in the depot to block and to absorb additional radiation.
In addition to the above ingredients of the water solution or slurry, such fluid may include metallic fines, such as lead and iron. These metallic fine materials can block transmission of radiation from radioactive material stored in the facility. Typically such fines will tend to reflect the radiation and to increase the likelihood that such radiation will encounter water molecules of the salt for absorption thereby.
The fines are metallic materials which are good absorbers or suppressors of radioactivity. The fines also may reflect or scatter the radioactive wave or particle. The fines may be retained in the slurry and then filtered out when they become too radioactive. An advantage of metallic fines over the hydrated salt is that the fines may be heavier than the salt and provide better shielding. The invention reduces the thickness of the walls and roof of the building to get the same effective shielding as was possible in the past using a much heavier structure.
Preferably the material of which the sidewalls are made includes water molecules, plastics and hydrogen-containing materials as part of panel construction. Such materials are good radiation shielding materials. The water molecules not only are part of the circulating fluid of the slurry, but the water of hydration molecules in the salt that is included in the slurry also provide for radiation shielding and absorption. Further, plastic material, such as that included, e.g. as the resin, of the Staytex material also is a relatively good radiation shielding and absorbing material--shielding due to the nature of the plastic and absorbing/shielding due to the water of hydration in the epsom salt included in the Staytex material itself. Additionally, it is known that hydrogen-containing material tends to provide shielding for radiation, and the polyester resin of which the Staytex material is formed includes an abundance of hydrogen molecules.
The panels, or the sidewalls, are made of materials including compounds containing water molecules, plastics and hydrogen-containing materials. Compounds containing water molecules may be any metal salt hydrate described above. In one embodiment, the plastic is a thermoplastic resin. In another embodiment, the plastic is a thermoset resin. Exemplary plastic materials include polyesters, polycarbonates, polyethers, and polyalkylene materials. Hydrogen-containing materials are materials containing an abundance of hydrogen molecules. For example, various resins such as polyester resins and polyalkylene resins such as polyethylene and polypropylene resins may be used.
Turning to FIG. 13, a modified treatment system 100 for treating the slurry after it has been circulated through the pipes 23 and/or elsewhere in the facility, includes a mixer 101, the filter 49, a recirculate/discard liquid valve 102, and the pump 42. The slurry is received by the mixer 101 where a precipitating agent is added. An exemplary precipitating agent is ethanol. For a water and epsom salt slurry, by adding sufficient quantity of ethanol thereto at the mixer 101, the epsom salt will precipitate out from the slurry and can relatively easily be filtered by the filter 49. The precipitating agent may be supplied from a separate reservoir 103 and a conventional dispensing control 104, which controls the amount of precipitating agent added to the slurry based on the known amount or measured amount of epsom salt (or the like) in the slurry. The removed precipitate and/or other solids can be directed along a path 105 to a drum or other storage container for storage in the facility, if desired or for removal from the facility and storage elsewhere. It is anticipated that the removed precipitate would be radioactive having absorbed radiation during circulation in the slurry; and, therefore, appropriate care in handling and storage is given, e.g., as is described herein.
After the solids have been removed at the filter 49, the liquid, e.g., water, can be directed by the valve 102 through pipe 106 and pump 42 for recirculation in the pipes 23 or elsewhere in the facility. Additional salt, e.g., epsom salt, or one or more of the above materials, may be added to the water prior to such recirculation. Alternatively, the water may be directed via the valve 102 and pipe 107 for discarding. If it has been sufficiently cleaned of radiation and/or other ingredients, the water may be discharged into the local water system, stream, lake, etc., and, if desired, the water may be further filtered by artificial or natural means, such as a filter, the earth, etc. prior to discarding.
Briefly referring back to FIG. 1, the toxic waste storage depot or facility 10 and building 11 thereof may include at or on the exposed surfaces thereof, e.g., on the roof 32 and/or on the sidewalls 31 a exposed above ground, solar panels 120 to receive solar energy and to convert that energy to electricity for use in operating the facility. One or more storage batteries or the like 121 may be used to store electrical energy from the solar panels 120. An electric generator 122 also may be included in the facility 10 to generate electricity from heat energy removed from the slurry in the heat exchanger(s) 45. The electricity from such electric generator may be used to operate the facility, such as to operate the pump(s) 42, and/or for other operations; alternatively or additionally, such electricity also may be fed back into the local power system or power company.
One or more detectors and/or other instruments generally designated 123 may be embedded within the sidewalls 31, floor(s), ceiling(s), etc. of the building 11. For example, the detectors may be molded into the respective walls, etc. Such detectors may be used to detect heat, radiation, humidity, pressure, or other characteristic or parameter. The detectors 123 may be connected to a monitor and control system 124, such as a computer, to provide information representing the detected characteristic thereto via connection lines 125, radio link, etc. The control system 124 may be on the premises of the building 11 or it may be off-site, as may be desired. Having the control system 124 off-site facilitates a remotely located operator to supervise operation of the equipment and stored materials in the building 11 and associated therewith and preferably to supervise several such facilities. Being able to provide off-site monitoring facilitates controlling inventory and helps to prevent the possibility of theft.
The monitor and control system 124 may store the information or may control operation of one or more parts of the depot 10 based on the information. Connection lines 126 provide such control information or function to such other components of the depot 10. For example, if the detected temperature inside the building 11 is relatively low or the detected radiation is relatively low, it may be possible to circulate in the pipes 23 a slurry which is relatively lightly loaded with epsom salt (or other radiation absorbing or shielding material); this being in contrast to a relatively high temperature or high radiation level in which case a greater loading or concentration of the epsom salt in the slurry may be desired and effected by the control system 124.
Turning, now, to FIG. 14, there is illustrated a slurry control system 130 for controlling the amount of additive, whether epsom salt, some other salt, some other ingredient, metal fines, etc., as described herein and equivalents thereof in the slurry. The slurry control system 130 may be interposed at various places in the fluid circulating or fluid flow system 17 of the invention; however, in the illustrated embodiment hereof the slurry control system 130 is located just upstream of the pump 42, which also is shown in FIGS. 1 and 13. In the portion of the flow system 17 shown in FIG. 13, the slurry control system 130 may be located between the recirculate/discard liquid control valve 102 and the pump 42.
One or more detectors 123 sends information to the controller 124 representing information based on which the controller determines and controls the amount of loading of the liquid by the epsom salt or other material being added to the water to form or to constitute the slurry. The additive, e.g, epsom salt, is supplied from a reservoir or storage container therefor, which is represented at 131. The liquid ingredient of the slurry is provided from a reservoir, source, or the recirculating valve 102 and is represented at 132.
The controller is coupled by lines 126a, 126b to the additive and liquid supplies 131, 132 and determines the amount of each delivered to the liquid/additive slurry formation device, such as a mixer 133 (blender or the like), in which the slurry is formed. The controller 124 also may be coupled by line 126c to the mixer 133 to control operation thereof to assure appropriate consistency, specific gravity, dissolving, particle mixing, etc. of the slurry ingredients. Also, the controller 124 may be connected by line 126d to the pump 42 to control the operation thereof, e.g., to determine the head pressure, flow volume, etc. of the slurry.
In operation of the toxic waste storage depot 10, by monitoring radiation, temperature, and/or the like, the slurry control system 130 is able to keep radioactivity at safe levels. For example, the amount of loading of the slurry with radiation absorbing and/or shielding material, such as epsom salt, the amount of radiation absorbed and/or blocked from transmitting from the building 11 can be controlled. By controlling the flow rate of slurry, the amount of heat removal from the building 11 can be controlled. By controlling flow rate, loading, and/or salt removal, e.g., by the precipitating method of FIG. 13 or by some other method, the amount of reloading of the slurry and amount of radiation subsequently absorbed can be controlled to provide safe operation for the facility 10 to store toxic waste, especially nuclear or radioactive waste without damaging leakage.
Another embodiment of building 141 in accordance with a modified toxic waste storage depot 10' of the invention is disclosed in FIG. 15. The storage depot 10' may be the same as the storage depot 10 described above, except that the building 111 is modified from the building 11. The building 141 is made of a combination of a steel or other strong and stiff supportive frame structure 142. Other exemplary materials for the frame structure 142 include aluminum, other metals, alloys, or the like, and/or synthetic materials, such as polymeric material or other material. The frame structure 142 includes a plurality of horizontal, vertical and diagonal rib-like members (also referred to below as "ribs"), struts or the like, such as C-shape, Z-shape, I-shape, etc. beams 143 of steel or some other material as mentioned or equivalents. These ribs are secured together to form a strong rigid structure. Wall panels, such as the pre-fabricated wall panels 33 described above, are inserted between and secured to the respective ribs 143 by conventional fasteners, such as screws, clips, adhesive material, etc. Such wall panels form the sidewalls 31 of the building 141. The floor 144 of the building 141 is made from concrete that can be poured in place or can be prefabricated. Preferably the floor 144 is poured in place to maximize integrity thereof. The floor 144 may be mounted by plural stilts 145 above the base 21 of the large hole 20 in the ground 12 or the floor 144 may be mounted on or poured directly onto the ground 12 over which the liner 22 preferably first is placed, as was described above. Alternatively, the floor 144 and roof 145 of the building 141 may be substantially the same as the floor 30 and roof 32 described above, although in the building 141 the floors and roof are supported from respective ribs 142. A portion of the building 141 and the sidewalls thereof preferably are located below ground level in a manner similar to the building 11 of FIG. 1, for example.
The building 141 is of modular construction. The sidewall panels 33 may be load bearing in which case the load capacity of the ribs 142 may be reduced compared to the load capacity thereof if the panels 33 were not load bearing. In the illustrated example of building 141, the transverse ceiling ribs 150 are Z-section steel beams and the longitudinal ceiling ribs 151 are C-section steel beams connected as shown. The floor structure includes transverse Z-section steel beams 1 52 and longitudinal C-section ribs 153. Vertical columns 154 and diagonal braces 155 are C-section steel beams. Other equivalent components may be used to construct the building 141 to provide the desired containment facility for toxic waste storage in accordance with the invention hereof.
It will be appreciated that the various features of the invention described in connection with one of the embodiments or drawings hereof may be used in connection with other embodiments and/or systems, devices, structures, etc., of the various other drawings hereof.